1. How much anhydrous CuSO4 in grams are required to prepare 700.0 mL of 0.30 M...
1. How much anhydrous CuSO4 in grams are required to prepare 700.0 mL of 0.30 M CuSO4 solution? Molar mass of CuSO4 = 159.62 g
2. A student determined the molar absorptivity of a copper (II) sulfate solution to be 2.81 M-1 cm-1 . If the absorbance of the given solution was 0.703, what was the concentration of the given solution? Assume the path length of solution 1.0 cm.
3. Why should you rinse the cuvette before you fill it up with the solution to be measured?
4. What is the purpose of determining λmax in this experiment? What might happen if you use wavelength other than λmax?
Homework Answers
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1. How much anhydrous CuSO4 in grams are required to prepare
700.0 mL of 0.30 M...
CuSO4• 5H20 -------> Custy + D u 2) What is the color for anhydrous salt of copper (II) sulfate (CuSO4)? What is...
CuSO4• 5H20 -------> Custy + D u 2) What is the color for anhydrous salt of copper (II) sulfate (CuSO4)? What is the color for ionic hydrate compound of copper (II) sulfate pentahydrate (CuSO4.5H2O)? 3) How would you test a colorless crystalline compound to determine whether it is a hydrate or not? 4) How many grams of CuSO4.5H20 are needed to prepare 50.0 mL of a 1.00 M CuSO4 solution? 5) Suppose you used the Procedure in this experiment to...
Question 8 Status: Tries remaining: 21 Points possible: 1.00 Suppose you measure the absorbance of a...
Question 8 Status: Tries remaining: 21 Points possible: 1.00 Suppose you measure the absorbance of a yellow dye solution in a 1.00 cm cuvette. cm what is The absorbance of the solution at 427 nm is 0.46. If the molar absorptivity of yellow dye at 427 nm is 27400 M the concentration of the solution? Answer: Question 9 Status: Tries remaining: 2 Points possible: 1.00 If you plot the absorbance measurements of solutions vs. their concentrations, what is the slope...
1) When CuSO SHO is heated, it decomposes to anhydrous CuSO4 and water. Complete and balance...
1) When CuSO SHO is heated, it decomposes to anhydrous CuSO4 and water. Complete and balance the following reaction, CuSO4+ 5HO 2) What is the color for anhydrous salt of copper (II) sulfate (CuSO.)? What is the color for ionic hydrate compound of copper (II) sulfate pentahydrate (CuSO. SH:O)? 3) How would you test a colorless crystalline compound to determine whether it is a hydrate or not? 4) How many grams of CuSO4 5H20 are needed to prepare 50,0 mL...
Name: Determination of Solution Concentration by Spectrophotometry PRELAB QUESTIONS 1. A student measures the absorbance of...
Name: Determination of Solution Concentration by Spectrophotometry PRELAB QUESTIONS 1. A student measures the absorbance of an unknown after placing a sample in a cuvette which contained some water. How will this affect the concentration he reports? 2. Explain why it is all right to leave water in the volumetric flask before you put in the 10.00 mL of your unknown. 3. A 1.3 x 10-M solution of an unknown substance has an absorbance of 0.345 at its max. a)...
Post LaboratorY Qustions A colored salution had a large absorbance peak at 690 nm Use the...
Post LaboratorY Qustions A colored salution had a large absorbance peak at 690 nm Use the visitle spectrum in your text or other reliable source to determine the color of this solution 2 A soft drink had a tertrazine also known as yellow #5 concentration of 1.75 x 10 M If a person drank two 12 ounce cans of this beverage for a vear (365 days). What mass of tartrazine would the person consume? Moleculer weight 534 g/mol for tartrazine....
1. Use the following data to construct a calibration curve and determine the concentration of unknown...
1. Use the following data to construct a calibration curve and determine the concentration of unknown as given. What is the molar absorptivity of the analyte? The compound solutions were measured in a 0.5 cm path length quartz cuvette. solution [X] (M) Absorbance At 254 nm Standard 1 Standard 2 Standard 3 Standard 4 Standard 5 Sample 0.03584 0.05719 0.1289 0.2305 0.3161 ??? 0.097 0.169 0.365 0.682 0.997 0.719
the guiding questions. the max absorbance is 460. Guiding questions complex turque . Compare the molar...
the
guiding questions. the max absorbance is 460.
Guiding questions complex turque . Compare the molar absorptivity coefficients you obtained with SCN and Fe" as limiting reagents. Would you expect them to be the same? Why or why not? (Week 1) • The accepted molar absorptivity coefficient for FeSCN is 7.0x10' M'cm''. Find the bias and relative bias of your values and suggest possible sources of errors. (Week 1) • Which molar absorptivity coefficient will you use to calculate the...
PROBLEM: Predict the molar absorptivity value of copper sulfate pentahydrate at 380 nm. Here's what I...
PROBLEM: Predict the molar absorptivity value of copper
sulfate pentahydrate at 380 nm.
Here's what I think I have to do:
I think I need to use beer's law. Abs=ebc; e=Abs/bc.
b is 1.66 cm. I think c is .400 M NiSO4, but I'm not sure. I
also think Abs is 0.758 given the graph. (If wavelength is 380 nm,
then it should be between 0.598 and 0.798, right?) My answer is
1.14 L/mol*cm, but not sure if I am...
Table 1. Concentrations of [Fe(Phen),1?, M, in water and UV- vis absorbance values recorded at 2...
Table 1. Concentrations of [Fe(Phen),1?, M, in water and UV- vis absorbance values recorded at 2 -505 nm. Concentration of [Fe(Phen)/, M Absorbance 9.500 x 10 0.999 4.250 x 10 0.480 0.219 2.125 10% 1.063 x 10 0.104 0.000 0.003 Table 2. UV-vis absorbance values of [Fe(phen)]* held at 35 °C after mixing with H SO, and recorded at 5 minute intervals (in water at max = 505 nm). Time (minutes) Absorbance 0.997 0.935 0.877 0.823 0.772 0.724 0.680 0.638...
answers for this pre/post lab Name: Date: Lab Section Colorimetric Pre/Postlab Questions 1. What iron species...
answers for this pre/post lab
Name: Date: Lab Section Colorimetric Pre/Postlab Questions 1. What iron species give rise to the orange color upon addition of 1,10-phenanthroline to an iron(II) solution? 2. How are percent transmittance and absorbance related algebraically? (Be able to convert %T to 4 and 4 to %7:) 3. What are the five fundamental components of a spectrophotometer? 4. State and define all terms (including units) in the Beer-Lambert law. 5. What is the purpose of preparing a...
CuSO4• 5H20 -------> Custy + D u 2) What is the color for anhydrous salt of copper (II) sulfate (CuSO4)? What is the color for ionic hydrate compound of copper (II) sulfate pentahydrate (CuSO4.5H2O)? 3) How would you test a colorless crystalline compound to determine whether it is a hydrate or not? 4) How many grams of CuSO4.5H20 are needed to prepare 50.0 mL of a 1.00 M CuSO4 solution? 5) Suppose you used the Procedure in this experiment to...
Question 8 Status: Tries remaining: 21 Points possible: 1.00 Suppose you measure the absorbance of a yellow dye solution in a 1.00 cm cuvette. cm what is The absorbance of the solution at 427 nm is 0.46. If the molar absorptivity of yellow dye at 427 nm is 27400 M the concentration of the solution? Answer: Question 9 Status: Tries remaining: 2 Points possible: 1.00 If you plot the absorbance measurements of solutions vs. their concentrations, what is the slope...
1) When CuSO SHO is heated, it decomposes to anhydrous CuSO4 and water. Complete and balance the following reaction, CuSO4+ 5HO 2) What is the color for anhydrous salt of copper (II) sulfate (CuSO.)? What is the color for ionic hydrate compound of copper (II) sulfate pentahydrate (CuSO. SH:O)? 3) How would you test a colorless crystalline compound to determine whether it is a hydrate or not? 4) How many grams of CuSO4 5H20 are needed to prepare 50,0 mL...
Name: Determination of Solution Concentration by Spectrophotometry PRELAB QUESTIONS 1. A student measures the absorbance of an unknown after placing a sample in a cuvette which contained some water. How will this affect the concentration he reports? 2. Explain why it is all right to leave water in the volumetric flask before you put in the 10.00 mL of your unknown. 3. A 1.3 x 10-M solution of an unknown substance has an absorbance of 0.345 at its max. a)...
Post LaboratorY Qustions A colored salution had a large absorbance peak at 690 nm Use the visitle spectrum in your text or other reliable source to determine the color of this solution 2 A soft drink had a tertrazine also known as yellow #5 concentration of 1.75 x 10 M If a person drank two 12 ounce cans of this beverage for a vear (365 days). What mass of tartrazine would the person consume? Moleculer weight 534 g/mol for tartrazine....
1. Use the following data to construct a calibration curve and determine the concentration of unknown as given. What is the molar absorptivity of the analyte? The compound solutions were measured in a 0.5 cm path length quartz cuvette. solution [X] (M) Absorbance At 254 nm Standard 1 Standard 2 Standard 3 Standard 4 Standard 5 Sample 0.03584 0.05719 0.1289 0.2305 0.3161 ??? 0.097 0.169 0.365 0.682 0.997 0.719
the
guiding questions. the max absorbance is 460.
Guiding questions complex turque . Compare the molar absorptivity coefficients you obtained with SCN and Fe" as limiting reagents. Would you expect them to be the same? Why or why not? (Week 1) • The accepted molar absorptivity coefficient for FeSCN is 7.0x10' M'cm''. Find the bias and relative bias of your values and suggest possible sources of errors. (Week 1) • Which molar absorptivity coefficient will you use to calculate the...
PROBLEM: Predict the molar absorptivity value of copper
sulfate pentahydrate at 380 nm.
Here's what I think I have to do:
I think I need to use beer's law. Abs=ebc; e=Abs/bc.
b is 1.66 cm. I think c is .400 M NiSO4, but I'm not sure. I
also think Abs is 0.758 given the graph. (If wavelength is 380 nm,
then it should be between 0.598 and 0.798, right?) My answer is
1.14 L/mol*cm, but not sure if I am...
Table 1. Concentrations of [Fe(Phen),1?, M, in water and UV- vis absorbance values recorded at 2 -505 nm. Concentration of [Fe(Phen)/, M Absorbance 9.500 x 10 0.999 4.250 x 10 0.480 0.219 2.125 10% 1.063 x 10 0.104 0.000 0.003 Table 2. UV-vis absorbance values of [Fe(phen)]* held at 35 °C after mixing with H SO, and recorded at 5 minute intervals (in water at max = 505 nm). Time (minutes) Absorbance 0.997 0.935 0.877 0.823 0.772 0.724 0.680 0.638...
answers for this pre/post lab
Name: Date: Lab Section Colorimetric Pre/Postlab Questions 1. What iron species give rise to the orange color upon addition of 1,10-phenanthroline to an iron(II) solution? 2. How are percent transmittance and absorbance related algebraically? (Be able to convert %T to 4 and 4 to %7:) 3. What are the five fundamental components of a spectrophotometer? 4. State and define all terms (including units) in the Beer-Lambert law. 5. What is the purpose of preparing a...
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