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(b) Iodine is found in organic forms in plants and animals and in inorganic forms in...

(b) Iodine is found in organic forms in plants and animals and in inorganic forms in natural water samples. Using suitable equations, explain the effect of added iodide on the distribution ratio for the solvent extraction of iodine from water samples. [5 marks]

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Students observe iodine crystals dissolving in equal volumes of two immiscible solvents, aqueous potassium iodide and cyclohexane, and familiarize themselves with the different colours of the two solutions. To each solution they add the other solvent, and observe the gradual extraction of the iodine from one layer to the other until an equilibrium distribution is reached. If the quantity of iodine and the volume of each solvent are the same in both tubes, they should be able to observe that the same equilibrium position has been reached in both tubes. Using further volumes of the two solvents, they can demonstrate that it is possible to achieve almost complete extraction from one solvent to the other.

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