Which proposed mechanism below is a correct option for the overall reaction shown? Overall reaction: F2(g)+CHF3(g)→HF(g)+CF4(g)...
Which proposed mechanism below is a correct option for the overall reaction shown? Overall reaction: F2(g)+CHF3(g)→HF(g)+CF4(g) Sum the reactions in each proposed mechanism to determine which mechanism is valid for the overall reaction.
Sum the reactions in each proposed mechanism to determine which mechanism is valid for the overall reaction.
A.] Step 1: F2(g)→2F(g) Step 2: H2(g)+F(g)+CF3(g)→HF(g)+CHF3(g) Step 3: F(g)+CF3(g)→CF4(g)
B.] Step 1: F2(g)→2F(g) Step 2: F(g)+CHF3(g)→HF(g)+CF3(g) Step 3: F(g)+CF3(g)→CF4(g)
Homework Answers
The mechanism B is valid for the given reaction. This can be determined as shown in the image below.
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Which proposed mechanism below is a correct option for the
overall reaction shown? Overall reaction:
F2(g)+CHF3(g)→HF(g)+CF4(g)...
Question 8 of 20 Using the equations H2(g) + F2 (g) → 2 HF (g) AH°...
Question 8 of 20 Using the equations H2(g) + F2 (g) → 2 HF (g) AH° = -79.2 kJ/mol C(s) + 2 F2 (g) → CF. (g) AH° = 141.3 kJ/mol 2 C(s) + 2 H2 (9) C2H4 (9) AH = -97.6 kJ/mol Determine the enthalpy for the reaction C2H4 (g) + 6 F2 (g) → 2 CF4 (9) + 4 HF (g). kJ/mol
Ozone decomposes to molecular oxygen: 2 O3(g) ⇋ 3 O2(g). The following is a proposed mechanism...
Ozone decomposes to molecular oxygen: 2 O3(g) ⇋ 3 O2(g). The
following is a proposed mechanism for the reaction:
Step 1: O3(g) ⇋ O2(g) + O(g) (fast) Step 2: O3(g) + O(g) ⇋ 2
O2(g) (slow)
Provide a valid rate law for the overall ozone decomposition
reaction based on this mechanism.
4. Ozone decomposes to molecular oxygen: 203(g) — 3 O2(g). The following is a proposed mechanism for the reaction: Step 1: 03(g) – O2(g) + O(g) (fast) Step 2:...
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1:...
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? k[N2O][H2] k[NO]2[H2] k[NO]2[H2]2 k[NO]1/2[H2] k[NO]2
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1:...
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO]1/2[H2] k[NO]2[H2] k[NO] [H2)2 k[N20][H2] k[NO]2
4. Below is a proposed mechanism for a reaction: Step 1. Step 2. C+E-F Step 3....
4. Below is a proposed mechanism for a reaction: Step 1. Step 2. C+E-F Step 3. F G A B C+D Fast equilibrium Slow Fast A. (2 points) What is the overall stoichiometry for this reaction? B. (2 points) Which step is the rate determining step? C. (6 points) If this mechanism is correct, what should the rate equation for this reaction be? (Make sure you include the fast equilibrium)
1. A proposed mechanism for a reaction is: 1221 (rapid equilibrium) I + H2 = H2...
1. A proposed mechanism for a reaction is: 1221 (rapid equilibrium) I + H2 = H2 (rapid equilibrium) H21 + 1 = 2 HI (slow) a. Write the overall balanced equation for this reaction. (4 pts.) b. Indicate which step is the rate determining step. (1 pt.) c. Based on the mechanism proposed, write the rate law for the overall reaction. (2 pts.) d. Using ki, ki, ka, etc., write the value for the overall rate constant k. (2 pts.)...
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) →...
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
6. The rate law for the following reaction is rate=k[NO2] (F2]: 2NO2(g) + F2(g) → 2NO2F(g)...
6. The rate law for the following reaction is rate=k[NO2] (F2]: 2NO2(g) + F2(g) → 2NO2F(g) The mechanism proposed for this reaction is as follows: (i) NO2(g) + F2(g) → NO2F(g) + F(g) (ii) NO2(g) + F(g) → NO2F(g) Which elementary step is the rate-determining step in this reaction? Explain your answer in 1-2 sentences.
Submit Question 33 of 50 For the chemical reaction H2 (g)+ F2 (g) 2 HF (g)...
Submit Question 33 of 50 For the chemical reaction H2 (g)+ F2 (g) 2 HF (g) AH = -79.2 kJ/mol. What is the enthalpy for the reaction 3 H2 (g)+3 F2 (g) 6 HF (g) kJ/mol 1 2 3 4 5 6 C 8 +- 0 x 100 O 7
Consider the reaction given below. H2(g) + F2(g) 2 HF(g) (a) Using thermodynamic data from the...
Consider the reaction given below.
H2(g) + F2(g)
2 HF(g)
(a) Using thermodynamic data from the course website, calculate
G° at 298 K.
kJ
(b) Calculate G at 298 K if the reaction mixture
consists of 5.1 atm of H2, 4.8 atm of F2, and
0.19 atm of HF.
kJ
Question 8 of 20 Using the equations H2(g) + F2 (g) → 2 HF (g) AH° = -79.2 kJ/mol C(s) + 2 F2 (g) → CF. (g) AH° = 141.3 kJ/mol 2 C(s) + 2 H2 (9) C2H4 (9) AH = -97.6 kJ/mol Determine the enthalpy for the reaction C2H4 (g) + 6 F2 (g) → 2 CF4 (9) + 4 HF (g). kJ/mol
Ozone decomposes to molecular oxygen: 2 O3(g) ⇋ 3 O2(g). The
following is a proposed mechanism for the reaction:
Step 1: O3(g) ⇋ O2(g) + O(g) (fast) Step 2: O3(g) + O(g) ⇋ 2
O2(g) (slow)
Provide a valid rate law for the overall ozone decomposition
reaction based on this mechanism.
4. Ozone decomposes to molecular oxygen: 203(g) — 3 O2(g). The following is a proposed mechanism for the reaction: Step 1: 03(g) – O2(g) + O(g) (fast) Step 2:...
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO]1/2[H2] k[NO]2[H2] k[NO] [H2)2 k[N20][H2] k[NO]2
4. Below is a proposed mechanism for a reaction: Step 1. Step 2. C+E-F Step 3. F G A B C+D Fast equilibrium Slow Fast A. (2 points) What is the overall stoichiometry for this reaction? B. (2 points) Which step is the rate determining step? C. (6 points) If this mechanism is correct, what should the rate equation for this reaction be? (Make sure you include the fast equilibrium)
1. A proposed mechanism for a reaction is: 1221 (rapid equilibrium) I + H2 = H2 (rapid equilibrium) H21 + 1 = 2 HI (slow) a. Write the overall balanced equation for this reaction. (4 pts.) b. Indicate which step is the rate determining step. (1 pt.) c. Based on the mechanism proposed, write the rate law for the overall reaction. (2 pts.) d. Using ki, ki, ka, etc., write the value for the overall rate constant k. (2 pts.)...
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
6. The rate law for the following reaction is rate=k[NO2] (F2]: 2NO2(g) + F2(g) → 2NO2F(g) The mechanism proposed for this reaction is as follows: (i) NO2(g) + F2(g) → NO2F(g) + F(g) (ii) NO2(g) + F(g) → NO2F(g) Which elementary step is the rate-determining step in this reaction? Explain your answer in 1-2 sentences.
Submit Question 33 of 50 For the chemical reaction H2 (g)+ F2 (g) 2 HF (g) AH = -79.2 kJ/mol. What is the enthalpy for the reaction 3 H2 (g)+3 F2 (g) 6 HF (g) kJ/mol 1 2 3 4 5 6 C 8 +- 0 x 100 O 7
Consider the reaction given below.
H2(g) + F2(g)
2 HF(g)
(a) Using thermodynamic data from the course website, calculate
G° at 298 K.
kJ
(b) Calculate G at 298 K if the reaction mixture
consists of 5.1 atm of H2, 4.8 atm of F2, and
0.19 atm of HF.
kJ
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