The (unbalanced) reduction potentials involved in this reaction are Cu2+ (aq) + 2e- -> Cu(s) E0...
The (unbalanced) reduction potentials involved in this reaction are
Cu2+ (aq) + 2e- -> Cu(s) E0 = 0.34V
NO3- (aq) + 3e- -> NO(g) E0= 0.96V
1)Write out the INDIVIDUAL balanced half reactions, identify which half-reaction is taking place at the anode and cathode and calculate the electrochemical potential of the reaction.
2) Suppose the Ph of the solution was increased so that [H+] = 0.1M, but the concentrations of all other species in solution were unchanged, Would the free energy become more negative, less negative or unchanged?
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The (unbalanced) reduction potentials involved in this reaction
are
Cu2+ (aq) + 2e- -> Cu(s) E0...
Write the half reactions and overall reaction for each cell with calculated overall potentials as shown...
Write the half reactions and overall reaction for each cell with calculated overall potentials as shown in Table 5-1. (Note: for the iron solutions the Nernst equation must be used) Pb(s) | Pb(NO3)2 (0.1M) || Cu(NO3)2 (0.1M) Cu(s) Zn(s) | Zn(NO3)2(0.1M) || Cu(NO3)2 (0.1M) Cu(s) Cds) | Ca(NO3)2 (0.1M) || Cu(NO3)2 (0.1M) | Cu(s) Cu() Cu(NO3)2(0.1M) Il Fe (0.1M/Fe? (0.1M graphite Pb(s) Pb(NO3)2(0.1M) Il Fe3(aq) (0.1M)/ Fe2(aq) (0.1MI graphite(s) Zns | Zn(NO3)2 (0.1M) || Pb(NO3)2 (0.1M) | Pb(s) Cdis Ca(NO3)2...
Standard Electrode Potentials at 25?C Reduction Half-Reaction E?(V) F2(g)+2e? ?2F?(aq) 2.87 Au3+(aq)+3e? ?Au(s) 1.50 Cl2(g)+2e? ?2Cl?(aq)...
Standard Electrode Potentials at 25?C Reduction Half-Reaction E?(V) F2(g)+2e? ?2F?(aq) 2.87 Au3+(aq)+3e? ?Au(s) 1.50 Cl2(g)+2e? ?2Cl?(aq) 1.36 O2(g)+4H+(aq)+4e? ?2H2O(l) 1.23 Br2(l)+2e? ?2Br?(aq) 1.09 NO3?(aq)+4H+(aq)+3e? ?NO(g)+2H2O(l) 0.96 Ag+(aq)+e? ?Ag(s) 0.80 I2(s)+2e? ?2I?(aq) 0.54 Cu2+(aq)+2e? ?Cu(s) 0.16 2H+(aq)+2e? ?H2(g) 0 Cr3+(aq)+3e? ?Cr(s) -0.73 2H2O(l)+2e? ?H2(g)+2OH?(aq) -0.83 Mn2+(aq)+2e? ?Mn(s) -1.18 How can the table be used to predict whether or not a metal will dissolve in HCl? In HNO3? Drag the terms on the left to the appropriate blanks on the right to...
4. A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:...
4. A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown: Cu2+(aq) + 2e Cu(s) Fe3+(aq) + 3e,-- Fe(s) +0.34V +0.77V What is the standard free energy change for the cell reaction of this galvanic cell?
Consider the balanced redox reaction below. 2Hg(I) + 2 Cu2 + (aq) +2CI-(aq)? Hg2CI2(aq) +2 Cu...
Consider the balanced redox reaction below. 2Hg(I) + 2 Cu2 + (aq) +2CI-(aq)? Hg2CI2(aq) +2 Cu (s) Standard reduction Potentials are given below. Standard Reduction Potentials Reduction Half Reaction Cu2+ (aq) +2e-? Cu (s) 0.34 27 What is the cell potential, Ecell for the following concentrations at 298 K? Cu2+)-0.02M (CI1-0.3M [Hg2Cl21-0.005M Express your answer in units of Volts. 321
A standard galvanic cell is constructed in which a Cu2+ Cu half cell acts as the...
A standard galvanic cell is constructed in which a Cu2+ Cu half cell acts as the cathode. Which of the following statements are correct? Hint: Refer to a table of standard reduction potentials. (Choose all that apply.) The cathode reaction is Cu -> Cu2+ + 2e The anode reaction could be Fe -> Fe2+ + 2e The anode compartment could be Aglag. Cu2+ is reduced at the cathode. In the external circuit, electrons flow from the other compartment to the...
Half-cell Potentials: Half Reaction: E value +0.80 V Agt + e → Ag Fe3+ + €...
Half-cell Potentials: Half Reaction: E value +0.80 V Agt + e → Ag Fe3+ + € → Fe2+ +0.77 v +0.34 V -0.13 V Cu2+ +2e → Cu Pb2+ + 2e - → Ib Ni2+ + 2e → Ni Cd2+ +2e → Cd -0.25 V -0.40 V Fe2+ + 2e → Fe -0.44 V Zn2+ + 2e → Zn -0.76 V Al3+ +3e → AI - 1.66 V Consider an electrochemical cell constructed from the following half cells, linked by...
calculate the cell potential of this reaction. Cu|Cu2+ (0.0100M)||Cu2+ (0.1M)|Cu . The half-cell reaction is Cu2+(aq)...
calculate the cell potential of this reaction. Cu|Cu2+ (0.0100M)||Cu2+ (0.1M)|Cu . The half-cell reaction is Cu2+(aq) + 2e- --> Cu(s) with standard potential Eo is 0.3419V
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
Consider the following UNBALANCED reaction IN ACIDIC SOLUTION: Cu(s) + NO3(aq) - -Cu2+ (aq) + NO()...
Consider the following UNBALANCED reaction IN ACIDIC SOLUTION: Cu(s) + NO3(aq) - -Cu2+ (aq) + NO() Provide the following information with the requested information. Make sure to show any work that is required for full credit. You may use the Eºcell potential table found here. a. (5) Species that is oxidized (be specific - i.e.identify which atom and if there are multiple atoms with different charges, identify the correct one) b. (5) Species that is reduced (same instructions as above)...
In an electrochemical cell composed of Cu(s)/Cu2+(aq, o.10M)||Cu2+(aq, 1.0M) |Cu(s), Which concentration of Cu would the...
In an electrochemical cell composed of Cu(s)/Cu2+(aq, o.10M)||Cu2+(aq, 1.0M) |Cu(s), Which concentration of Cu would the anode be sitting in? Which concentration of Cu would the cathode be sitting in?
Write the half reactions and overall reaction for each cell with calculated overall potentials as shown in Table 5-1. (Note: for the iron solutions the Nernst equation must be used) Pb(s) | Pb(NO3)2 (0.1M) || Cu(NO3)2 (0.1M) Cu(s) Zn(s) | Zn(NO3)2(0.1M) || Cu(NO3)2 (0.1M) Cu(s) Cds) | Ca(NO3)2 (0.1M) || Cu(NO3)2 (0.1M) | Cu(s) Cu() Cu(NO3)2(0.1M) Il Fe (0.1M/Fe? (0.1M graphite Pb(s) Pb(NO3)2(0.1M) Il Fe3(aq) (0.1M)/ Fe2(aq) (0.1MI graphite(s) Zns | Zn(NO3)2 (0.1M) || Pb(NO3)2 (0.1M) | Pb(s) Cdis Ca(NO3)2...
4. A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown: Cu2+(aq) + 2e Cu(s) Fe3+(aq) + 3e,-- Fe(s) +0.34V +0.77V What is the standard free energy change for the cell reaction of this galvanic cell?
Consider the balanced redox reaction below. 2Hg(I) + 2 Cu2 + (aq) +2CI-(aq)? Hg2CI2(aq) +2 Cu (s) Standard reduction Potentials are given below. Standard Reduction Potentials Reduction Half Reaction Cu2+ (aq) +2e-? Cu (s) 0.34 27 What is the cell potential, Ecell for the following concentrations at 298 K? Cu2+)-0.02M (CI1-0.3M [Hg2Cl21-0.005M Express your answer in units of Volts. 321
A standard galvanic cell is constructed in which a Cu2+ Cu half cell acts as the cathode. Which of the following statements are correct? Hint: Refer to a table of standard reduction potentials. (Choose all that apply.) The cathode reaction is Cu -> Cu2+ + 2e The anode reaction could be Fe -> Fe2+ + 2e The anode compartment could be Aglag. Cu2+ is reduced at the cathode. In the external circuit, electrons flow from the other compartment to the...
Half-cell Potentials: Half Reaction: E value +0.80 V Agt + e → Ag Fe3+ + € → Fe2+ +0.77 v +0.34 V -0.13 V Cu2+ +2e → Cu Pb2+ + 2e - → Ib Ni2+ + 2e → Ni Cd2+ +2e → Cd -0.25 V -0.40 V Fe2+ + 2e → Fe -0.44 V Zn2+ + 2e → Zn -0.76 V Al3+ +3e → AI - 1.66 V Consider an electrochemical cell constructed from the following half cells, linked by...
Consider the following UNBALANCED reaction IN ACIDIC SOLUTION: Cu(s) + NO3(aq) - -Cu2+ (aq) + NO() Provide the following information with the requested information. Make sure to show any work that is required for full credit. You may use the Eºcell potential table found here. a. (5) Species that is oxidized (be specific - i.e.identify which atom and if there are multiple atoms with different charges, identify the correct one) b. (5) Species that is reduced (same instructions as above)...
In an electrochemical cell composed of Cu(s)/Cu2+(aq, o.10M)||Cu2+(aq, 1.0M) |Cu(s), Which concentration of Cu would the anode be sitting in? Which concentration of Cu would the cathode be sitting in?
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