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1. a) Why does biphenyl have a higher Rf value than either benzophenone or triphenylmethanol? Exp...

1.

a) Why does biphenyl have a higher Rf value than either benzophenone or triphenylmethanol? Explain based on the structures and their effect on mobility in the TLC process.

b) Which compound, benzophenone or triphenylmethanol has a higher Rf value? Explain, based on their structures, how you can predict this.

c) You developed your TLC using a 10% mixture of diethyl ether in petroleum ether. Petroleum ether is a mixture of non-polar alkanes, so this TLC solvent is composed of 10% Et2O / 90% alkanes. If you were to have used the opposite ratio instead (i.e., 90% Et2O / 10% alkanes) how would the Rf value of the following substances change? Choose the one most likely option for each:

Biphenyl:                    [increase]       [decrease]      [remain the same]

Benzophenone:         [increase]       [decrease]      [remain the same]

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