PCC is a mild oxidising agent and oxidize the Alcohol to aldehyde. Then Grignard reagent is more reactive towards aldehyde than Ketone. Hence grigGrig reagent gives secondary alcohol with aldehyde first then protection of alcohol by ether since OH is Grignard reagent sensitive. Then reaction of ketone with Grignard reagent gives tertiary alcohol them followed by deprotection of Ether by Lewis acid.
11. Synthesis of Phosphorus ylide with methyl bromide then Wittig reaction gives required alkene.
Extra credit (10 pts) 2140 b Show how to synthesize 2-methyl-2,6-heptandiol from 5-hydroxy-2-pent...
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. он ethanol OH 4-methylheptan-4-ol
1. Which Wittig reagent would be used to synthesize 2 CH-CH=P(CAH) CH=P(CHẠh. P(CH3)3 CH,CH,CH-P(CH3)3 IV 2. What is the correct IUPAC name for the following compound? 6 eye 3. What is the correct structure for 7-methyl-4-octanone? 3 4. The products, D and E, of the following reaction sequence, S "CN HCI HCN CH.NO H20 heat would be: CH2CH2CN CH,CH,MgBe HO E ? ether Show how you would synthesize the following compound, beginning with 1-butene, Bromobenzene and any necessary additional reagents....
Using methyl iodide, CH3I, and sodium acetylide as the sources of carbon atoms, show how to synthesize meso-2,3-dibromobutane. You may use any other needed reagents or solvents, provided they do not supply carbon atoms to the final product. About 5 steps are required. Please write out the formulas of the reagents. Free Response (10 pts each) Read instructions carefully and write out your answers in detail. 1. Using methyl iodide, CHI, and sodium acetylide, Nat:CECH, as the sources of carbon...
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH ethanol 4-methylheptan-4-01
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH ethanol 4-methylheptan-4-ol
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH ethanol 4-methylheptan-4-ol
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH ethanol OH 4-methylheptan-4-ol
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH OH ethanol 4-methylheptan-4-ol
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH ethanol OH 4-methylheptan-4-ol
Extra Credit: There will be no partial credit. Answers must be correct. (10 pts) Show how you would accomplish the following synthetic conversion starting with ethanol as the only source of organic carbon atoms. You may use any necessary inorganic reagent and solvent. Show all reaction steps, reagents and conditions used. OH OH ethanol 4-methylheptan-4-ol