If at all Solid gas euillibrium is considered at
t=-180c , the pressure will
be
e(26.396-4293.9273-18)Pa
according to the given equation, pressure=14145.85 Pa
for gas- solid equillibrium
Similarly according to the given equation in the question, pressure of liquid gas equilibrium =14827.16Pa.
Pressure given is 18kPa which is near to Liquid- gas equilibrium and as pressure is higher, definitely, HCN is in liquid state, because at higher pressure for the same temperature entropy of a substance will be less and therefore, a substance tend to be in liquid state.
According to clapeyron equation,
dPdT=∆HT*∆V,
∆V=Volume of vapour because, volume of vapor is≫>volume of
liquid, i.e equation becomes dPdT=
∆HT*VVVV=volume of
vapor=RT/P
, classius clapeyron equation is valid here which is ln (P2/P1) =
∆HR*1T1-1T2,
T1= -180C, here vapor pressure is
14827.16Pa= P1,
P2= 18000pa, here T2 is calculated by the equation given for
vapour- liquid equilibrium in the question and we get the
temperature as 258.826 K.
Latent heat of vaporisation = 27810.952213 J/mol
Vapour pressure curves of HCN are described by following equations (p/Pa, T/K) hp= 26.396 In p- 2...
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