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Propose a structure for a compound whose(M)" is 86 and (M-1)", is 5% of the molecular ion. Its ir shows an absorption at 1720 cm1 and its 'H NMR displays δ 1.1 (d, 6H), δ 2.1 (s, 3 H), an...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
parent ion at m/z 102 (M*), IR peaks at 1740 and 1150 cm 10. Propose a...
parent ion at m/z 102 (M*), IR peaks at 1740 and 1150 cm 10. Propose a structure for a molecule whose mass spectrum shows which gave the following 'H NMR spectrum.) 6 1 septet 2 5 0 6 PPM 11. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 116 (M*) with at 1740 and 1150 cm1 which gave the following H NMR spectrum. base peak at m/z 43, IR peaks 6 1 2...
Extra Credits (5 points) Propose a possible structure for a compound with molecular formula C-H12O2 that...
Extra Credits (5 points) Propose a possible structure for a compound with molecular formula C-H12O2 that shows absorption at 1720 cm-' and no absorption in the range of 1500 - 1700 cm' or 2600 - 2800 cm in its IR spectrum and only three signals in its 'H NMR spectrum.
A compound with molecular formula C7H160 displays the following IR and 'H-NMR spectra. The 13C NMR...
A compound with molecular formula C7H160 displays the following IR and 'H-NMR spectra. The 13C NMR data suggest that there is some symmetry within the molecule. a) Calculate the degrees of unsaturation (DU) for the compound in the space provided below. DU = b) Identify and label the two indicated peaks in the IR spectrum in the boxes provided. Identify and label ALL peaks in the 'H NMR spectrum below. The numbers given on the 'H NMR are integration values...
The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum...
The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum of this compound has a broad peak between 3200 and 3550 cm-1. The 1H NMR spectrum of A shows the following peaks: a triplet at d 0.9, a singlet at d 1.1, one more singlet at d 1.15, and a quartet at d 1.6. The area ratio of these peaks is 3:6:1:2. The 13C NMR contains 4 signals. In the space below, propose a...
An unknown compound A has an empirical formula of c3h6o and a molecular ion peak in...
An unknown compound A has an empirical formula of c3h6o and a
molecular ion peak in its mass spectrum at m/z 116. It also has no
IR absorption at 3200-3600cm^-1 but shows a peak at 1740cm^-1. The
H NMR spectra data of A is given below in table format. Use this
information to answer questions a-d below.
9 (15 Points). An unknown compound A has empiricl rmula of C,HO and a molecular ion peak in its mass spectrum at an...
9. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z...
9. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 102 (M), IR peaks at 1740 and 1150 cm which gave the following 'H NMR spectrum.) 2 PPM
2. Draw the structure of the compound with molecular formula C H1N exhibiting a triplet at...
2. Draw the structure of the compound with molecular formula C H1N exhibiting a triplet at 8 0.9 (6H), a singlet at 8 1.1 (1H), a sextet at 01.3 (4H), a quintet at 8 1.4 (4H) and a triplet at 8 2.6 (4H) in its 'H NMR spectrum. Its IR spectrum shows a medium absorption band near 3400 cm' and its 13C NMR spectrum showed peaks at 13.7, 20.5, 30.4 and 49.2. (2 pts.) 3. Synthesize the following by showing...
Question 3) Propose a structure consistent with the following spectral data for a compound C&H..0) IR...
Question 3) Propose a structure consistent with the following spectral data for a compound C&H..0) IR 3100 (broad, strong). 1710 (strong) cm''; 'H NMR 1.05 (triplet; 3H), 2.40 (triplet: 2H), 3.46 (quartet, 2H), 3.61 (triplet, 2H), 12.01 (broad singlet, 1H) (10 points) puy!!! Chemical Shift in 'H NMR --C-HE! 2.1-2.6 C-H 2.3-2.9 (benzylic) (vinylic) 4.5-6.0 -C-H 9.0-10.0 (aldehydic) C-H (allylic) 1.6-2.8 6.5-8,0 -c-H| (phenyl) 3.2-4.2 C-H 0.7-1 (alkyl) 1110 7 32 1 8 (ppm) I-¢-H| 22-4.2 - C- H 2.7-4.2...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
parent ion at m/z 102 (M*), IR peaks at 1740 and 1150 cm 10. Propose a structure for a molecule whose mass spectrum shows which gave the following 'H NMR spectrum.) 6 1 septet 2 5 0 6 PPM 11. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 116 (M*) with at 1740 and 1150 cm1 which gave the following H NMR spectrum. base peak at m/z 43, IR peaks 6 1 2...
Extra Credits (5 points) Propose a possible structure for a compound with molecular formula C-H12O2 that shows absorption at 1720 cm-' and no absorption in the range of 1500 - 1700 cm' or 2600 - 2800 cm in its IR spectrum and only three signals in its 'H NMR spectrum.
A compound with molecular formula C7H160 displays the following IR and 'H-NMR spectra. The 13C NMR data suggest that there is some symmetry within the molecule. a) Calculate the degrees of unsaturation (DU) for the compound in the space provided below. DU = b) Identify and label the two indicated peaks in the IR spectrum in the boxes provided. Identify and label ALL peaks in the 'H NMR spectrum below. The numbers given on the 'H NMR are integration values...
An unknown compound A has an empirical formula of c3h6o and a
molecular ion peak in its mass spectrum at m/z 116. It also has no
IR absorption at 3200-3600cm^-1 but shows a peak at 1740cm^-1. The
H NMR spectra data of A is given below in table format. Use this
information to answer questions a-d below.
9 (15 Points). An unknown compound A has empiricl rmula of C,HO and a molecular ion peak in its mass spectrum at an...
9. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 102 (M), IR peaks at 1740 and 1150 cm which gave the following 'H NMR spectrum.) 2 PPM
2. Draw the structure of the compound with molecular formula C H1N exhibiting a triplet at 8 0.9 (6H), a singlet at 8 1.1 (1H), a sextet at 01.3 (4H), a quintet at 8 1.4 (4H) and a triplet at 8 2.6 (4H) in its 'H NMR spectrum. Its IR spectrum shows a medium absorption band near 3400 cm' and its 13C NMR spectrum showed peaks at 13.7, 20.5, 30.4 and 49.2. (2 pts.) 3. Synthesize the following by showing...
Question 3) Propose a structure consistent with the following spectral data for a compound C&H..0) IR 3100 (broad, strong). 1710 (strong) cm''; 'H NMR 1.05 (triplet; 3H), 2.40 (triplet: 2H), 3.46 (quartet, 2H), 3.61 (triplet, 2H), 12.01 (broad singlet, 1H) (10 points) puy!!! Chemical Shift in 'H NMR --C-HE! 2.1-2.6 C-H 2.3-2.9 (benzylic) (vinylic) 4.5-6.0 -C-H 9.0-10.0 (aldehydic) C-H (allylic) 1.6-2.8 6.5-8,0 -c-H| (phenyl) 3.2-4.2 C-H 0.7-1 (alkyl) 1110 7 32 1 8 (ppm) I-¢-H| 22-4.2 - C- H 2.7-4.2...
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