What is the expected geometry around the central atom in the following? (using cation and anion) .[Pt(NH3)4][PtCl6] ***Pt complexes do not usually assume a tetrahedral shape .[Cr(NH3)4(SCN)2][Cr(NH3)2...
What is the expected geometry around the central atom in the
following? (using cation and anion)
.[Pt(NH3)4][PtCl6] ***Pt complexes do not usually assume a
tetrahedral shape
.[Cr(NH3)4(SCN)2][Cr(NH3)2(SCN)4]
Homework Answers
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What is the expected geometry around the central atom in the following? (using cation and anion) .[Pt(NH3)4][PtCl6] ***Pt complexes do not usually assume a tetrahedral shape .[Cr(NH3)4(SCN)2][Cr(NH3)2...
4. Consider the following complexes. Na, [Fe(ox),] [Cr(H2O) (NHJ) SO, [Pt(en)(ONO)CI] Write the coordination sphere for...
4. Consider the following complexes. Na, [Fe(ox),] [Cr(H2O) (NHJ) SO, [Pt(en)(ONO)CI] Write the coordination sphere for the complexes I, II and III. [3 marks] in each of the Determine the oxidation state of the central atom coordination complex [3 marks] Determine the coordination number in each of the complexes. [3 marks) Name each of the complex using IUPAC system [6 marks) Draw the molecular geometry of complex II. [2 marks] Using Crystal Field Theory, draw the energy diagram of the...
2. Knowing that the groups of electrons around the central atom affect the molecule shape, how...
2. Knowing that the groups of electrons around the central
atom affect the molecule shape, how do you think this will affect
the interactions between two molecules called intermolecular
interactions?
Guidelines for Drawing Lewis Structures STEP 1: Determine the total number of valence electrons for the molecule. STEP 2: Determine the skeletal structure (arrangement of atoms) of the compound. For simple compounds the singular atom will be in the center with the others arranged around it. Attach each bonded atom...
What is the coordination number for each of the following complexes or compounds? [Co(NH3)4Cl2]+ [Ca(EDTA)]2− [Pt(NH3)4]2+...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
What is the name of the following inorganic complexes a. [Pt(NH3)3C13] b. [Co(NH3)2(H20)2Cl2] c. [Re(dien)Br2Cl] d....
What is the name of the following inorganic
complexes
a. [Pt(NH3)3C13] b. [Co(NH3)2(H20)2Cl2] c. [Re(dien)Br2Cl] d. [Co(EDTA)] e. [Cr(phen) (NH3)2C12]*
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)"....
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
Chemistry 2A Lab 11: Molecular Geometry Molecule or Ion Lewis Diagram Central Molecular Bond Atom Geometry Polari...
Chemistry 2A Lab 11: Molecular Geometry Molecule or Ion Lewis Diagram Central Molecular Bond Atom Geometry Polarity Lone Pairs Symmetry Molecular Polarity Atom Bonding Pairs 13. IO2-1 14. SO42 15. HCN. 16. NO; To determine overall molecular polarity follow the procedure below: 1. Identify the central atom. The central atom is the least electronegative element. Hydrogen is not a central atom. 2. Place all other atoms around the central atom. 3. Calculate the total number of valence electrons. Include the...
1. For each of the following complexes, give the electron configurations of the d-type M Os,...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the str...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the structural formula (lewis formula) for the following: a. A charged monodentate ligand (answer cannot be a halide ion) b. A polydentate ligand c. The CO ligand, not used in the laboratory. Is it likely CO can form a coordinate covalent bond from more than one atom? Explain. NC CN Ni Geometry of Coordination Compounds A compounds geometry (i.e., how...
Zinc forms the cation, Zn2+. A mystery anion X is represented as X2. Given this information,...
Zinc forms the cation, Zn2+. A mystery anion X is represented as X2. Given this information, what is the molecular formula of the salt it forms with zinc? (Chemical formula use subscript numbers, but for this question any required numbers may be formatted normally. Also, do not insert any spaces between the elements.) Answer: Library Home Students According to the VSEPR electron pairs in the valence energy level repel each other and are therefore arranged as far apart as possible....
Answer the following on a separate sheet of paper. 1. Using the data collected for PF,...
Answer the following on a separate sheet of paper. 1. Using the data collected for PF, SF, and CIF, what structural comments can be made about molecules with more than four groups (charge clouds) around the central atom? 2. Select which structure is preferred and discuss why? SC 3. To assess the stability of the axial versus equatorial positions for a trigonal bipyramidal structure, a computer program was used to determine the energy to assess SF, with the lone pair...
4. Consider the following complexes. Na, [Fe(ox),] [Cr(H2O) (NHJ) SO, [Pt(en)(ONO)CI] Write the coordination sphere for the complexes I, II and III. [3 marks] in each of the Determine the oxidation state of the central atom coordination complex [3 marks] Determine the coordination number in each of the complexes. [3 marks) Name each of the complex using IUPAC system [6 marks) Draw the molecular geometry of complex II. [2 marks] Using Crystal Field Theory, draw the energy diagram of the...
2. Knowing that the groups of electrons around the central
atom affect the molecule shape, how do you think this will affect
the interactions between two molecules called intermolecular
interactions?
Guidelines for Drawing Lewis Structures STEP 1: Determine the total number of valence electrons for the molecule. STEP 2: Determine the skeletal structure (arrangement of atoms) of the compound. For simple compounds the singular atom will be in the center with the others arranged around it. Attach each bonded atom...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
What is the name of the following inorganic
complexes
a. [Pt(NH3)3C13] b. [Co(NH3)2(H20)2Cl2] c. [Re(dien)Br2Cl] d. [Co(EDTA)] e. [Cr(phen) (NH3)2C12]*
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
Chemistry 2A Lab 11: Molecular Geometry Molecule or Ion Lewis Diagram Central Molecular Bond Atom Geometry Polarity Lone Pairs Symmetry Molecular Polarity Atom Bonding Pairs 13. IO2-1 14. SO42 15. HCN. 16. NO; To determine overall molecular polarity follow the procedure below: 1. Identify the central atom. The central atom is the least electronegative element. Hydrogen is not a central atom. 2. Place all other atoms around the central atom. 3. Calculate the total number of valence electrons. Include the...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the structural formula (lewis formula) for the following: a. A charged monodentate ligand (answer cannot be a halide ion) b. A polydentate ligand c. The CO ligand, not used in the laboratory. Is it likely CO can form a coordinate covalent bond from more than one atom? Explain. NC CN Ni Geometry of Coordination Compounds A compounds geometry (i.e., how...
Zinc forms the cation, Zn2+. A mystery anion X is represented as X2. Given this information, what is the molecular formula of the salt it forms with zinc? (Chemical formula use subscript numbers, but for this question any required numbers may be formatted normally. Also, do not insert any spaces between the elements.) Answer: Library Home Students According to the VSEPR electron pairs in the valence energy level repel each other and are therefore arranged as far apart as possible....
Answer the following on a separate sheet of paper. 1. Using the data collected for PF, SF, and CIF, what structural comments can be made about molecules with more than four groups (charge clouds) around the central atom? 2. Select which structure is preferred and discuss why? SC 3. To assess the stability of the axial versus equatorial positions for a trigonal bipyramidal structure, a computer program was used to determine the energy to assess SF, with the lone pair...
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