Question

Please evaluate the IR spectrum. Provide a structure and note any important peaks corresponding to the structure.

It was an experiment using:

isoamyl alcohol + acetic acid

sulfuric acid as the catalyst

and the products are isoamyl acetate and water. Thank you so much!!!95 卜诒 卜” 90 85 寸 80 75 70 65 E 60 ー 55 50 45 40 35 30 25 20 4000 3500 3000 2500 2000 Wavenumbers (cm-1) 1500 1000 500

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Answer #1

Esterification Reaction

он он Acetic acid Isoamyl alcohol isoamyl acetate

Stretching and bending of the functional group of isoamyl acetate

Absorption, cm-1

Stretching/Bending

Functional group

2958

Sp3 C-H Stretching

-CH3, -CH2, -CH

2871

Sp3 C-H Stretching

-CH3, -CH2, -CH

1739

-C=O stretching (carbonyl-ester)

-COOR ester group

1465

Sp3 C-H bending

-CH3, -CH2, -CH

1387

Sp3 C-H bending

-CH3, -CH2, -CH

1227

-C-O Stretching

COOR ester group

1055

-C-O Stretching

COOR ester group

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