Consider the compound [PtBr2(en)(ox)] (en = ethylenediamine; ox = oxalate). (a) Draw the structures to represent all of...
Consider the compound [PtBr2(en)(ox)] (en = ethylenediamine; ox = oxalate).
(a) Draw the structures to represent all of the possible isomers.
(b) Describe the type of isomerism which links the different isomers.
Homework Answers
![- The possible isomers for [Pt Br (en) (ox)] are - AN . Br---t- NH, I PA OS I 1 T I and II (or) I and I are geometrical isome](http://img.homeworklib.com/questions/e63c7da0-013d-11ea-a5d2-736fcb1845e4.png?x-oss-process=image/resize,w_560)
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Consider the compound [PtBr2(en)(ox)] (en = ethylenediamine; ox = oxalate). (a) Draw the structures to represent all of...
State the types of isomerism that may be exhibited by the following complexes, and draw structures...
State the types of isomerism that may be exhibited by the following complexes, and draw structures of the isomers: (a) [Co(en)2(ox)]+ (b) [Cr(ox)2(OH2)2]-, (c) [PtCl2(PPh3)2], (d) [PtCl2(Ph2PCH2CH2PPh2)] and (e) [Co(en)(NH3)2Cl2]+.
The oxalate dianion or 'ox' (C2042) can act as a bidentate ligand. a) Explain what is...
The oxalate dianion or 'ox' (C2042) can act as a bidentate ligand. a) Explain what is meant by the term 'bidentate". B3. (1 mark) b) Reaction of FeClh.6H20 (1 mmol) with 'ox (3 mmol) in aqueous solution forms several octahedral complexes. Draw all possible isomers for the product of this reaction, indicating the charge on the complex ions (3 marks) c) Give the name for the type of stereoisomerism observed and hence assign and label each of the stereoisomers from...
Analyze each pair of compounds structures represent. Your cho cach pair of compounds below. Identify which...
Analyze each pair of compounds structures represent. Your cho cach pair of compounds below. Identify which class of isomers each pair of s represent. Your choices are: (i) constitutional, (ii) conformational, (iii) omers, (iv) diastereomer or (v) identical (non-isomers). Only one label for each pair should be used. For each case show work (drawings, (R)/(S), rotation of bonds, chair- "ps, etc) which led you to each answer for the pairs below. Any differences of answers between you and your peers...
Give the relationships between the following pairs of structures. State whether they represent the same compound,...
Give the relationships between the following pairs of
structures. State whether they represent the same compound,
different compounds, or they are constitutional isomers of each
other.
Give the relationships between the following pairs of structures. State whether they represent the same compound, different compounds, or they are constitutional mers of each other CH2C1CHCICH3 and CH CHCic H2C1 (ii) and Gii) CH2- CHCH2CH and iv CH3CH2CHClCH2C1 and CH3CHCH2Cl HeCl
Which kinds of isomerism could the compound [Cr(en)2Cl2]Br engage in? Mark all that apply. Recommended time:...
Which kinds of isomerism could the compound [Cr(en)2Cl2]Br engage in? Mark all that apply. Recommended time: 5 minutes Linkage isomerism Geometric isomerism Optical isomerism Coordination sphere isomerism This compound does not display any of these forms of isomerism.
draw the products that are expected when the following compound is treates with a Grubbs catalyst....
draw the products that are expected when the following
compound is treates with a Grubbs catalyst. If several products or
isomers are possible, draw all structures.
no
further information. only the compound with question was
given
Your answer is incorrect. Try again. Draw the products that are expected when the following compound is treated with a Grubbs catalyst. If several products or isomers are possible, draw all structures CH, CH, Edit HC CH,
draw the products that are expected when the following compound is treated with a Grubbs catalyst....
draw the products that are expected when the following
compound is treated with a Grubbs catalyst. If several products or
isomers are possible, draw all structures.
Got this one wrong, please help.
Your answer is incorrect. Try again. Draw the products that are expected when the following compound is treated with a Grubbs catalyst. If several products or isomers are possible, draw all struct CH Edit HC LINK TO TEXT
Draw each of the complexes below as well as all possible isomers. a. tris(aquo)trichlorocobalt(III)Co(Cl)3(H2O)3 b. bis(ethylenediammine)dinitroiron(III)...
Draw each of the complexes below as well as all possible isomers. a. tris(aquo)trichlorocobalt(III)Co(Cl)3(H2O)3 b. bis(ethylenediammine)dinitroiron(III) Fe(en)2(NO2)2 This is an octahedral geometry as En is bidentate ethylenediamine:(en) NH2--C--C--NH2 nitro: NO2, bonded through N
The following pair of structures represent: C CH3-CH-CH2-CH, CH3-CH2-CH-CH y y CNS CA CH3 the same compound structu...
The following pair of structures represent: C CH3-CH-CH2-CH, CH3-CH2-CH-CH y y CNS CA CH3 the same compound structural isomers different compounds O cis-trans isomers
1. Draw the structures of: a) (Z) 2-iodo-3-methyl-2-heptene b) cis non-3-en-5 yne Give the IUPAC name...
1. Draw the structures of: a) (Z) 2-iodo-3-methyl-2-heptene b) cis non-3-en-5 yne Give the IUPAC name of the following compounds, including steochemistry. a) F CH2CH2Br CH3CE 2. a) Draw the most stable chair conformation of cis 1,3-difluorocyclohexane. b) Draw a Newman projection of 2-iodo-3-methylpentane looking down the 3. Compound X has the formula CoHB2Br4. Compound X reacts with excess H2/Pd to give CATHa6Bra. How many does compound X have? Show how you got your answer. rings 4. For each pair...
The oxalate dianion or 'ox' (C2042) can act as a bidentate ligand. a) Explain what is meant by the term 'bidentate". B3. (1 mark) b) Reaction of FeClh.6H20 (1 mmol) with 'ox (3 mmol) in aqueous solution forms several octahedral complexes. Draw all possible isomers for the product of this reaction, indicating the charge on the complex ions (3 marks) c) Give the name for the type of stereoisomerism observed and hence assign and label each of the stereoisomers from...
Analyze each pair of compounds structures represent. Your cho cach pair of compounds below. Identify which class of isomers each pair of s represent. Your choices are: (i) constitutional, (ii) conformational, (iii) omers, (iv) diastereomer or (v) identical (non-isomers). Only one label for each pair should be used. For each case show work (drawings, (R)/(S), rotation of bonds, chair- "ps, etc) which led you to each answer for the pairs below. Any differences of answers between you and your peers...
Give the relationships between the following pairs of
structures. State whether they represent the same compound,
different compounds, or they are constitutional isomers of each
other.
Give the relationships between the following pairs of structures. State whether they represent the same compound, different compounds, or they are constitutional mers of each other CH2C1CHCICH3 and CH CHCic H2C1 (ii) and Gii) CH2- CHCH2CH and iv CH3CH2CHClCH2C1 and CH3CHCH2Cl HeCl
Which kinds of isomerism could the compound [Cr(en)2Cl2]Br engage in? Mark all that apply. Recommended time: 5 minutes Linkage isomerism Geometric isomerism Optical isomerism Coordination sphere isomerism This compound does not display any of these forms of isomerism.
draw the products that are expected when the following
compound is treates with a Grubbs catalyst. If several products or
isomers are possible, draw all structures.
no
further information. only the compound with question was
given
Your answer is incorrect. Try again. Draw the products that are expected when the following compound is treated with a Grubbs catalyst. If several products or isomers are possible, draw all structures CH, CH, Edit HC CH,
draw the products that are expected when the following
compound is treated with a Grubbs catalyst. If several products or
isomers are possible, draw all structures.
Got this one wrong, please help.
Your answer is incorrect. Try again. Draw the products that are expected when the following compound is treated with a Grubbs catalyst. If several products or isomers are possible, draw all struct CH Edit HC LINK TO TEXT
The following pair of structures represent: C CH3-CH-CH2-CH, CH3-CH2-CH-CH y y CNS CA CH3 the same compound structural isomers different compounds O cis-trans isomers
1. Draw the structures of: a) (Z) 2-iodo-3-methyl-2-heptene b) cis non-3-en-5 yne Give the IUPAC name of the following compounds, including steochemistry. a) F CH2CH2Br CH3CE 2. a) Draw the most stable chair conformation of cis 1,3-difluorocyclohexane. b) Draw a Newman projection of 2-iodo-3-methylpentane looking down the 3. Compound X has the formula CoHB2Br4. Compound X reacts with excess H2/Pd to give CATHa6Bra. How many does compound X have? Show how you got your answer. rings 4. For each pair...
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