Draw each of the complexes below as well as all possible isomers. a. tris(aquo)trichlorocobalt(III)Co(Cl)3(H2O)3 b. bis(ethylenediammine)dinitroiron(III)...
Draw each of the complexes below as well as all possible isomers.
a. tris(aquo)trichlorocobalt(III)Co(Cl)3(H2O)3
b. bis(ethylenediammine)dinitroiron(III) Fe(en)2(NO2)2
This is an octahedral geometry as En is bidentate
ethylenediamine:(en) NH2--C--C--NH2 nitro: NO2, bonded through N
Homework Answers
Cis -90° angle between two same ligands
Trans - 180° angle between two same ligands (no.of ligands are less)
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Draw each of the complexes below as well as all possible
isomers.
a. tris(aquo)trichlorocobalt(III)Co(Cl)3(H2O)3
b. bis(ethylenediammine)dinitroiron(III)...
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH;...
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH; <en (H2NCH2CH2NH2) NO2 <CN <CO Formula Name # of lone de [Cr. (NH3)3 (+20)})( triamminetriaquachromium(III) chloride [Fe(NH3).](NO2) hexaammineiron (111) nitrate [pt leng (12232 dithicyanodi(ethylenediamine)platinum(IV) chloride [Co(C204)(CO)]* Owlbunyoleation contu) lon ammonium tetraiodicuprate(II) INHO), [LUIGI Ke[Fe(ONO).] [ Fel NH3)6] hexaammineiron(III) hexahydroxochromate(III) [Co(H2NCH2CH2NH3)4](SO4)3 | +r15 4+ hy • he ºlfa wine) ¢e bal} (1) v10a4e pentaaquahydroxoiron(III) ion [Fe(H2E), GH) +2. (NH4)[Ni(O2)2(H2O)2] ammunium cinquabiscova lato) nickelate CI) AN...
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)"....
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
(i) explain how they differ. b. (ii) Explain how the following reaction was used to deduce the mechanism of inner sphere electron transfer. [Co(NH,),Cl]Cr(Hd+SH,OCo(H,O)+ [Cr(HO),ci+5NH 8 marks]...
(i) explain how they differ. b. (ii) Explain how the following reaction was used to deduce the mechanism of inner sphere electron transfer. [Co(NH,),Cl]Cr(Hd+SH,OCo(H,O)+ [Cr(HO),ci+5NH 8 marks] (i) Given the following ligands, suggest which one you would use as a chelating agent to treat an excess of Fe(III). Explain your choice. c. HS SH он HS NH2 Ci) Assuming an octahedral geometry, draw the strueture (inecluding any possible isomers) of the neutral Fe(III) complex that would be formed if it...
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and...
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE): Are you (1) confident; (2) somewhat confident; or (3) unsure/guessing?
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE):...
2.(1) What does it mean when we say a transition metal complex (or a molecule) is...
2.(1) What does it mean when we say a transition metal complex (or a molecule) is chiral? 3.(3) Give the name or formula, as appropriate, for: a) [Co(CO)s]CO3 b) Ks[Fe(CN) 6] c) diaquabis(ethylenediamine)chromium(II) nitrate 4.(3) Give the coordination number, geometry, and hybridization of cobalt in [Co(NO2)2(en)2]2 5.(5) Draw all possible isomers of [CrNH)h(en)FJ. Label them as either geometrical or optical.
1. (6 pts.) Consider the coordination compound Rh(C)(CO)(PPhs)2: Draw the two possible isomers for this square...
1. (6 pts.) Consider the coordination compound Rh(C)(CO)(PPhs)2: Draw the two possible isomers for this square planar complex. What type of stereoisomers are these complexes? Why would no isomers exist for this complex if it had a tetrahedral geometry? a. b. c.
please do answer all the questions below. thank you For each of the following complexes, draw...
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...
Would appreciate as many answers as possible please and thank you! Will rate regardless 1. What...
Would appreciate as many answers as possible please and thank
you! Will rate regardless
1. What kind of molecular orbital (cor) is formed between the combinations below? sono apdo foge 8 8241 dyz 8.8min de 2. What is a 3 (delta) bond? 3. a) Build the molecular orbital energy diagram for the following molecules, O3, O2 and Oy b) Calculate the bond order for the three molecules, and justify which one is more stable. 4. Give chemical names for the...
Circle the pairs of compounds that are isomers of each other: (a) [Co(en)_3]Cl_3 and [Co(en)_3]Br_3 (b)...
Circle the pairs of compounds that are isomers of each other: (a) [Co(en)_3]Cl_3 and [Co(en)_3]Br_3 (b) [Co(H_2O)_4 Br_2]Cl and [Co(H_2O)_4BrCl]Br (c) [Cr(H_2O)_2(CO_3)_2]^2+ and [Cr(H_2O)_2(CO)_2(O_2)_2]^2+ (d) trans-[Pt(NH_3)_2Cl_2] and [Pt(NH_3)_3Cl]Cl Circle the appropriate description of the distinction between "geometric isomers" and "optical isomers": (a) Geometric isomers have a different set of bonds. optical isomers have the same set of bonds. (b) Geometric isomers differ in the spatial arrangement of bonds. In optical isomers the arrangement of bonds is the same. (c) Geometric...
[Co(en)2(H2O)(Cl)]3[Ni(CN)4]2 For the nickel portion of the complex, determine the number of d electrons and given...
[Co(en)2(H2O)(Cl)]3[Ni(CN)4]2 For the nickel portion of the complex, determine the number of d electrons and given the possible geometry(s) would the complex be a high spin or low spin complex.
Nomenclature Coordinate Complexes | <Br< SCN < Cl< O=N-0 <F <OH <C:0-(oxalato) < 0,2-<H2O <SCN <NH; <en (H2NCH2CH2NH2) NO2 <CN <CO Formula Name # of lone de [Cr. (NH3)3 (+20)})( triamminetriaquachromium(III) chloride [Fe(NH3).](NO2) hexaammineiron (111) nitrate [pt leng (12232 dithicyanodi(ethylenediamine)platinum(IV) chloride [Co(C204)(CO)]* Owlbunyoleation contu) lon ammonium tetraiodicuprate(II) INHO), [LUIGI Ke[Fe(ONO).] [ Fel NH3)6] hexaammineiron(III) hexahydroxochromate(III) [Co(H2NCH2CH2NH3)4](SO4)3 | +r15 4+ hy • he ºlfa wine) ¢e bal} (1) v10a4e pentaaquahydroxoiron(III) ion [Fe(H2E), GH) +2. (NH4)[Ni(O2)2(H2O)2] ammunium cinquabiscova lato) nickelate CI) AN...
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
(i) explain how they differ. b. (ii) Explain how the following reaction was used to deduce the mechanism of inner sphere electron transfer. [Co(NH,),Cl]Cr(Hd+SH,OCo(H,O)+ [Cr(HO),ci+5NH 8 marks] (i) Given the following ligands, suggest which one you would use as a chelating agent to treat an excess of Fe(III). Explain your choice. c. HS SH он HS NH2 Ci) Assuming an octahedral geometry, draw the strueture (inecluding any possible isomers) of the neutral Fe(III) complex that would be formed if it...
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE): Are you (1) confident; (2) somewhat confident; or (3) unsure/guessing?
21. Which of the following are coordination isomers? (a) cis-[CoCl2(en)2]Cl and trans-[CoCl2(en)2]Cl (b) [Cr(NH3)[Fe(CN) ] and [Fe(NH3)6][Cr(CN)] (c) [CoBr(NH3)sSO4 and [CrSO4(NH3)s]Br (d) [Co(NO2)(NH3)s]Cl2 and [Cr(ONO)(NH3)s] Cl2 (e) Both (b) and (c) Review your answer (CIRCLE):...
2.(1) What does it mean when we say a transition metal complex (or a molecule) is chiral? 3.(3) Give the name or formula, as appropriate, for: a) [Co(CO)s]CO3 b) Ks[Fe(CN) 6] c) diaquabis(ethylenediamine)chromium(II) nitrate 4.(3) Give the coordination number, geometry, and hybridization of cobalt in [Co(NO2)2(en)2]2 5.(5) Draw all possible isomers of [CrNH)h(en)FJ. Label them as either geometrical or optical.
1. (6 pts.) Consider the coordination compound Rh(C)(CO)(PPhs)2: Draw the two possible isomers for this square planar complex. What type of stereoisomers are these complexes? Why would no isomers exist for this complex if it had a tetrahedral geometry? a. b. c.
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...
Would appreciate as many answers as possible please and thank
you! Will rate regardless
1. What kind of molecular orbital (cor) is formed between the combinations below? sono apdo foge 8 8241 dyz 8.8min de 2. What is a 3 (delta) bond? 3. a) Build the molecular orbital energy diagram for the following molecules, O3, O2 and Oy b) Calculate the bond order for the three molecules, and justify which one is more stable. 4. Give chemical names for the...
Circle the pairs of compounds that are isomers of each other: (a) [Co(en)_3]Cl_3 and [Co(en)_3]Br_3 (b) [Co(H_2O)_4 Br_2]Cl and [Co(H_2O)_4BrCl]Br (c) [Cr(H_2O)_2(CO_3)_2]^2+ and [Cr(H_2O)_2(CO)_2(O_2)_2]^2+ (d) trans-[Pt(NH_3)_2Cl_2] and [Pt(NH_3)_3Cl]Cl Circle the appropriate description of the distinction between "geometric isomers" and "optical isomers": (a) Geometric isomers have a different set of bonds. optical isomers have the same set of bonds. (b) Geometric isomers differ in the spatial arrangement of bonds. In optical isomers the arrangement of bonds is the same. (c) Geometric...
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