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For the following reaction, the concentration of A and the amount of time required to decrease that concentration t...
The half-life of a reaction, t1/2, is the time it takes for the reactant concentration [A]...
The half-life of a reaction,
t1/2, is the time it takes for the reactant concentration [A] to
decrease by half. For example, after one half-life the
concentration falls from the initial concentration [A]0 to [A]0/2,
after a second half-life to [A]0/4, after a third half-life to
[A]0/8, and so on. on. For a first-order reaction, the half-life is
constant. It depends only on the rate constant k and not on the
reactant concentration. It is expressed as t1/2=0.693k For a...
A decomposition reaction has a half-life that is directly proportional to the initial concentration of the...
A decomposition reaction has a half-life that is directly proportional to the initial concentration of the reactant. What is the order of the reaction? Geologists can estimate the age of rocks by their uranium-238 content. The uranium is incorporated in the rock as it hardens and then decays with first-order kinetics and a half-life of 4.5 billion years. A rock is found to contain 83.4% of the amount of uranium-238 that it contained when it was formed. (The amount that...
Dr. Raphael Shell created a concentration vs time graph for the following chemical reaction
Dr. Raphael Shell created a concentration vs time graph for the following chemical reaction: 2 AB2 〓 4 B + 2 A. He observed that it took one hour to complete the first half-life, 30 min to complete its second half-life and 15 minutes to complete the third half-life. Also, doubling or tripling the concentration of the reactant shows no effect on the rate of reaction.a) Determine the (general or incomplete) RATE LAW for this reaction based on the information provided above. b) Using...
The integrated rate law allow chemists to predict the reactant concentration after a certain amount of...
The integrated rate law allow chemists to predict the reactant concentration after a certain amount of time, or the time it would take for a certain concentration to be reached. The integrated rate law for a first-order reaction is: [A] = [A]oe -Rt Now say we are particularly interested in the time it would take for the concentration to become one-half of its initial value. Then we could substitute Z" for [A] and rearrange the equation to: A) 1/2= 0093...
1. If the rate constant of a reaction increases by 2.5 when the temperature is increased...
1. If the rate constant of a reaction increases by 2.5 when the temperature is increased from 25 C to 34 C, then what is the activation energy (in kJ/mole) of the reactions? 2. If a reaction is first order with a rate constant of 4.48 x 10 ^ -2 sec ^-1, how long is required for 3/4 of the initial concentration of reactant to be used up? 3. Which statement is true or NOT regarding the experimental determination of...
The integrated rate law allows chemists to predict the reactant concentration after a certain amount of...
The integrated rate law allows
chemists to predict the reactant concentration after a certain
amount of time, or the time it would take for a certain
concentration to be reached. The integrated rate law for a
first-order reaction is: [A]=[A]0e−kt Now say we are particularly
interested in the time it would take for the concentration to
become one-half of its initial value. Then we could substitute
[A]02 for [A] and rearrange the equation to: t1/2=0.693k This
equation calculates the time...
The half-life of a reaction, t1/2, is the time required for one-half of a reactant to...
The half-life of a reaction, t1/2, is the time required for one-half of a reactant to be consumed. It is the time during which the amount of reactant or its concentration decreases to one-half of its initial value. Determine the half-life for the reaction in Part B using the integrated rate law, given that the initial concentration is 1.85 mol⋅L−1 and the rate constant is 0.0016 mol⋅L−1⋅s−1 . Express your answer to two significant figures and include the appropriate units.
Most of the time, the rate of a reaction depends on the concentration of the reactant....
Most of the time, the rate of a reaction depends on the
concentration of the reactant. In the case of second-order
reactions, the rate is proportional to the square of the
concentration of the reactant.
Select the image to explore the simulation, which will help you
to understand how second-order reactions are identified by the
nature of their plots. You can also observe the rate law for
different reactions.
In the simulation, you can select one of the three different...
8. In the reaction A products the initial concentration of A is 0.52M and the concentration...
8. In the reaction A products the initial concentration of A is 0.52M and the concentration is 0.12 M after 150.0 min. What is the value of the rate constant, k, in M min'? What is the half-life? k=0.0027 M min"!, t12=97.5 min 9. Consider the following reaction: N2(g) + 3H2(g) + 2NH3(g) (K = 2.41x 10-3) Given 2.00 mole of N2(g), 4.5 mole of H2(g), and 1.5 mole of NH3(g) are mixed in a 5.00 L flask, determine the...
2. Answer the following questions by connecting the half-life of each first-order reaction to the rate...
2. Answer the following questions by connecting the half-life of each first-order reaction to the rate constant. a. The rate constant of a first-order reaction is 2.43 × 10–2 min–1. What is the half-life of the reaction? (2 points) b. A first-order reaction has a rate constant of 0.547 min-1. How long will it take a reactant concentration 0.14 M to decrease to 0.07 M? (2 points) c. The half-life of a first-order reaction is 5.47 min. What is the...
The half-life of a reaction,
t1/2, is the time it takes for the reactant concentration [A] to
decrease by half. For example, after one half-life the
concentration falls from the initial concentration [A]0 to [A]0/2,
after a second half-life to [A]0/4, after a third half-life to
[A]0/8, and so on. on. For a first-order reaction, the half-life is
constant. It depends only on the rate constant k and not on the
reactant concentration. It is expressed as t1/2=0.693k For a...
The integrated rate law allow chemists to predict the reactant concentration after a certain amount of time, or the time it would take for a certain concentration to be reached. The integrated rate law for a first-order reaction is: [A] = [A]oe -Rt Now say we are particularly interested in the time it would take for the concentration to become one-half of its initial value. Then we could substitute Z" for [A] and rearrange the equation to: A) 1/2= 0093...
The integrated rate law allows
chemists to predict the reactant concentration after a certain
amount of time, or the time it would take for a certain
concentration to be reached. The integrated rate law for a
first-order reaction is: [A]=[A]0e−kt Now say we are particularly
interested in the time it would take for the concentration to
become one-half of its initial value. Then we could substitute
[A]02 for [A] and rearrange the equation to: t1/2=0.693k This
equation calculates the time...
Most of the time, the rate of a reaction depends on the
concentration of the reactant. In the case of second-order
reactions, the rate is proportional to the square of the
concentration of the reactant.
Select the image to explore the simulation, which will help you
to understand how second-order reactions are identified by the
nature of their plots. You can also observe the rate law for
different reactions.
In the simulation, you can select one of the three different...
8. In the reaction A products the initial concentration of A is 0.52M and the concentration is 0.12 M after 150.0 min. What is the value of the rate constant, k, in M min'? What is the half-life? k=0.0027 M min"!, t12=97.5 min 9. Consider the following reaction: N2(g) + 3H2(g) + 2NH3(g) (K = 2.41x 10-3) Given 2.00 mole of N2(g), 4.5 mole of H2(g), and 1.5 mole of NH3(g) are mixed in a 5.00 L flask, determine the...
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