1. If the rate constant of a reaction increases by 2.5 when the temperature is increased...
1. If the rate constant of a reaction increases by 2.5 when the temperature is increased from 25 C to 34 C, then what is the activation energy (in kJ/mole) of the reactions?
2. If a reaction is first order with a rate constant of 4.48 x 10 ^ -2 sec ^-1, how long is required for 3/4 of the initial concentration of reactant to be used up?
3. Which statement is true or NOT regarding the experimental determination of a rate law? Provide reasoning for your choice, and why others are NOT TRUE?
- The instantaneous rate at the midway point of the reaction is used to determine the exponents and rate law for that equation.
- The average rate of reaction at the midway point of the reaction is used to determine the exponents and rate law for that equation.
4. Which statement is TRUE about the half - life of a first - order reaction? Show reasoning for why others are incorrect.
- A larger rate constant corresponds to a longer half - life.
- The half - life is directly proportional to the original concentration of the reactant.
- The half - life is directly proportional to the final concentration of the reactant.
- The half - life is inversely proportional to the rate constant.
- The half - life is not affected by the change in temperature.
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1. If the rate constant of a reaction increases by 2.5
when the temperature is increased...
QUESTION 1 Variable(s) that affect rate include: temperature concentration pressure of gasses All of the above...
QUESTION 1 Variable(s) that affect rate include: temperature concentration pressure of gasses All of the above a and b only 1 points QUESTION 2 The rate constant (k) for a reaction: has units of M/s. changes with temperature is different for different concentrations of reactants All of the above b and c 1 points QUESTION 3 If a reactant is 2nd order, doubling the concentration of the reactant will: double the rate of the reaction triple the rate...
13) Give the characteristic of a second order reaction having only one reactant A) The rate...
13) Give the characteristic of a second order reaction having only one reactant A) The rate of the reaction is not proportional to the concentration of the reactant. B) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant C) The rate of the reaction is proportional to the square root of the concentration of the reactant D) The rate of the reaction is directly proportional to the concentration of the reactant. E)...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k k and not on the reactant concentration. It is expressed as t1/2=0.693k t 1 / 2 = 0.693 k For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as t1/2=1k[A]0. A certain first-order reaction (A→products A → p r o d u c t s ) has a rate constant of 9.30×10−3...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k and not on the reactant concentration. It is expressed as t 1/2 = 0.693 k For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as t 1/2 = 1 k[A ] 0 Part A A certain first-order reaction ( A→products ) has a rate constant of 9.90×10−3 s −1 at 45 ∘...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k and not on the reactant concentration. It is expressed as 0.693 - 1/2K For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as 1/2 k(Alo Part A A certain first-order reaction (A>products) has a rate constant of 9.60x10 s-1 at45 C. How many minutes does it take for the concentration of the...
2. Answer the following questions by connecting the half-life of each first-order reaction to the rate...
2. Answer the following questions by connecting the half-life of each first-order reaction to the rate constant. a. The rate constant of a first-order reaction is 2.43 × 10–2 min–1. What is the half-life of the reaction? (2 points) b. A first-order reaction has a rate constant of 0.547 min-1. How long will it take a reactant concentration 0.14 M to decrease to 0.07 M? (2 points) c. The half-life of a first-order reaction is 5.47 min. What is the...
For the following reaction, the concentration of A and the amount of time required to decrease that concentration t...
For the following reaction, the concentration of A and the amount of time required to decrease that concentration to one-half of the initial concentration, (vz, are directly proportional. Therefore, a decrease in concentration of A shows a proportional decrease in the half life, tv2. A products What is the order of this reaction? 2 If the rate constant for this reaction is o.0493 M s-1at 400 C, what is the half-life of this reaction, given an initial concentration of 0.821...
The integrated rate law allows chemists to predict the reactant concentration after a certain amount of...
The integrated rate law allows
chemists to predict the reactant concentration after a certain
amount of time, or the time it would take for a certain
concentration to be reached. The integrated rate law for a
first-order reaction is: [A]=[A]0e−kt Now say we are particularly
interested in the time it would take for the concentration to
become one-half of its initial value. Then we could substitute
[A]02 for [A] and rearrange the equation to: t1/2=0.693k This
equation calculates the time...
chem ll Select all quantities that are involved in an integrated rate law. time temperature activation...
chem ll
Select all quantities that are involved in an integrated rate law. time temperature activation energy concentration of reactant rate overall order rate constant intermediates half-life
The integrated rate law allow chemists to predict the reactant concentration after a certain amount of...
The integrated rate law allow chemists to predict the reactant concentration after a certain amount of time, or the time it would take for a certain concentration to be reached. The integrated rate law for a first-order reaction is: [A] = [A]oe -Rt Now say we are particularly interested in the time it would take for the concentration to become one-half of its initial value. Then we could substitute Z" for [A] and rearrange the equation to: A) 1/2= 0093...
13) Give the characteristic of a second order reaction having only one reactant A) The rate of the reaction is not proportional to the concentration of the reactant. B) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant C) The rate of the reaction is proportional to the square root of the concentration of the reactant D) The rate of the reaction is directly proportional to the concentration of the reactant. E)...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k and not on the reactant concentration. It is expressed as 0.693 - 1/2K For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as 1/2 k(Alo Part A A certain first-order reaction (A>products) has a rate constant of 9.60x10 s-1 at45 C. How many minutes does it take for the concentration of the...
For the following reaction, the concentration of A and the amount of time required to decrease that concentration to one-half of the initial concentration, (vz, are directly proportional. Therefore, a decrease in concentration of A shows a proportional decrease in the half life, tv2. A products What is the order of this reaction? 2 If the rate constant for this reaction is o.0493 M s-1at 400 C, what is the half-life of this reaction, given an initial concentration of 0.821...
The integrated rate law allows
chemists to predict the reactant concentration after a certain
amount of time, or the time it would take for a certain
concentration to be reached. The integrated rate law for a
first-order reaction is: [A]=[A]0e−kt Now say we are particularly
interested in the time it would take for the concentration to
become one-half of its initial value. Then we could substitute
[A]02 for [A] and rearrange the equation to: t1/2=0.693k This
equation calculates the time...
chem ll
Select all quantities that are involved in an integrated rate law. time temperature activation energy concentration of reactant rate overall order rate constant intermediates half-life
The integrated rate law allow chemists to predict the reactant concentration after a certain amount of time, or the time it would take for a certain concentration to be reached. The integrated rate law for a first-order reaction is: [A] = [A]oe -Rt Now say we are particularly interested in the time it would take for the concentration to become one-half of its initial value. Then we could substitute Z" for [A] and rearrange the equation to: A) 1/2= 0093...
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