4. Propose the scheme of the synthesis of trans-2-chlorocyclohexanol from chlorocyclohexane 5. Complete the following r...
Complete each of the following reactions.
H20, H2SO4 CO3H H3C H2CH3 H3C CH (1) BH3, THF (2) H202, NaOH H2CH3 CH22, Zn(Cu) H3C H2CHa (1) Hg(OpCCHa)2-H2O (2) NaBH4, NaOH
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1. BH3-THF 2. Ho, H202 C)1. Hg(OAc)2, H2O/THF 2. NaBH4 D)1. Hg(O2CCF3)2 CH3OH 2. NaBH4 E) NaOH, H20
1) R'-MgBr in THF 2)H,o NaH Ho or OH PAA X2. H20 1) Hg(OAc)2, R'OH 2) NaBH4, NaOH, H20 Os0 NaHSO, H2O I) 2)CH, SCH HyIO HBr ROOR 1)BH3. THF 2)H202, NaOH, H2O Mg, THF PBr3 NaOH )OTHF 2) H30 CrOj. H,SO, 1) NaH 2)RXDMF "О-R DMF PCC DCM ) THF 2) H3O+ SOCI pyridine Li Hexanes
3. For every reaction chose suitable reagents and conditions: OH LCHE H + enantiomer SCH LH + enantiomer OCH UCH Reagents and conditions: a. H20, 60% H2SO4, 0-10°C b. H, Pt 1). Hg(OCOCH3)2, THF, CH-OH; 2). NaBH, CH3OH 1). BH3, THF; 2). H202, NaOH, H2O HBr, hv, (PhCOO), (NOTE: hv means light-promotes radical reactions) HBr, CH:COOH Bra, CCL, 0-(-5)°C
In each reaction box, place the best reagent and conditions from the list below OH 1) 2) 3) OH Br2 H2CrO4 H202, NaOH, H20 BH3/THF PCI Cl2, H2O H2SO4 (conc.) dilute H3O* NaBH4 in EtOH
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2, NaOH; 3. PCC O 1. BHz – THF; 2. H2O2, NaOH; 3. H, CrO4 01. 03; 2. DMS 01. Hg(OAC)2, H2O; 2. NaBH4; 3. PCC Predict the product of the following reaction scheme: 2LIATH H2O OH OH Predict the product for the following reaction | | Identify the reaction sequence of reactions that can achieve the following transformation a- O (1) Br2, CCl4: (2)...
5. propose an efficient synthesis plan for each of the following
reactions.
6.Before moving on to N-nucleophiles, let’s check your memory on
some ketone reactions.
5. Now, straight from our textbook, propose an efficient synthesis plan for each of the following reactions. ره ماه را OH و . Ph Ah 6. Before moving on to N-nucleophiles, let's check your memory on some ketone reactions. 1. PhMgBr 2. H30* NaBH4, EtOH 1. LAH 2. H2O Zn(Hg), HCI
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Draw the major product for each of the following reactions.
Please include detailed explanations.
Print Periodic Table Ebook Question 18 of 20 (1 point)x Incorrect 1) BH3 THF 2) H202, NaOH H3C H3 CH3 H3C H3 H3C ??? 1) Hg(OAc)2. H20 2) NaBH4 H3 H3 ? H3 H2O [H2SO4] H3C CH2 H3C
2. Draw the major product(s) from the reaction of the starting material below with the following reagents: (12 marks) (a) (b) (1) BH3, THF (2) H2O2, NaOH, H2O Cl in excess EtOH (0) I-CI (d) (1) O3. CH CI: (2) Zn, acetic acid (e) (1) (1) OsO4, THF (2) H2S (1) Hg(OOCCH3)2, H2O (2) NaBH4, NaOH, H2O