see experiment 1 and 2:
[NO2] becomes 1.10/0.650 = 1.7 times
[O3] is constant
rate becomes 3.96/2.34 = 1.7 times
so, order of NO2 is 1
see experiment 2 and 3:
[NO2] becomes 1.76/1.1 = 1.6
[O3] 1.4/0.8 = 1.75
rate becomes 11.09/3.96 = 2.80
Since 1.16*1.75 = 2.80
Order of NO2 and O3 are both 1
so, order of O3 is 1
Rate law is:
rate = k*[NO2]*[O3]
Put values from 1st row of table in rate law
rate = k*[NO2]*[O3]
2.34*10^4 = k*0.65*0.8
k = 4.50*10^4 M-1.s-1
Answer: 4.50*10^4 M-1.s-1
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