Question

What can be said about an endothermic reaction with a negative entropy change? The reaction is What can be said about...

What can be said about an endothermic reaction with a negative entropy change?

The reaction is

What can be said about an endothermic reaction with a negative entropy change?

spontaneous at all temperatures.
spontaneous at high temperatures.
spontaneous at low temperatures.
spontaneous in the reverse direction at all temperatures.
nonspontaneous in either direction at all temperatures.
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Answer #1

Ans: spontaneous in the reverse direction at all temperatures.

?G = ?H -T?S

For spontaneous reactions, ?G = -ve

Given that endothermic reaction with a negative entropy change.

?H = +ve ?S= -ve

?G = ?H -T?S = +ve - T (-ve) = +ve

Therefore, the given reaction is non-spontaneous in forward direction.

Reverse direction:

Given that endothermic reaction with a negative entropy change. Then, ?H = +ve ?S= -ve

For reverse reaction ?H = -ve ?S= +ve

?G = ?H -T?S = -ve - T (+ve) = -ve

?G = -ve

Therefore, the given reaction is spontaneous in reverse direction.

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