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Concepts and reason

Bond energy, also known as bond enthalpy, is defined as the energy required for breaking the chemical bonds in a molecule. Bond energy is the measurement of the strength of a chemical bond. A chemical reaction involves the breaking and making of bonds. The amount of energy required for the breaking of bonds and the amount of energy released for bond-making is also represented as bond energy.

Fundamentals

The arbitrary reaction is given below:

aA bB
cC + dD

The formula to calculate the bond enthalpy or bond energy of reaction is given below:

Дне
=bond energy of reactant - bondenergy of product
reaction
AHcaction is enthalpy of reaction

The given data

:-65.07 kJ /mol
АН

Average С-Н
bond energy in CH4 415kJ/mol

Number ofС-Н
bond in 1 molCH4 4

The given reaction is

C,H(g)g)>2CH,(g)

Average Н-Н
bond energy in H2 436kJ/mol

Number ofН-Н
bond in 1 molН, -1

Average С-с
bond energy in CH 347kJ/mol

Number ofС-с
bond in 1 molCH1

Number ofС-Н
bond in 1 molCH6

Calculate the average bond energy of the reaction.

Ан
reaction
bondenergy of reactant ->bondenergy of product
=2I(1xEv(CC)+(6xE(C- H)+(1xE (H-H)]-[8xE(C-H)]
avg
avg
avg
avg

Substitute the values.

-65.07 [(1x347)+(6xE (CH)436)]-[8x415]
avg
(С-Н) - 2471.93
6xЕ
avg
C-H 411.98KJ /mol

Therefore, the average С-Н
bond energy of С,Н,
is411.98KJ/mol.

The given reaction is

C,H(g)+2(g) 2CH,(g)
=-202.21kJ/mol
гхn

Average bond energy in

Number ofbond in 2 molН, 3 2

Average C C
bond energy in C,H6kJ/mol

Number ofC C
bond in 1 molС,Н, -1

Number ofbond in 1 molCH 4

Calculate the average bond energy of the reaction.

bondenergy of reactant - >bond energy of product
AH
reaction
=I(1xE(C C)+(4xE(C-H)+(2x E
(H-H)]-[8xEav(C-H)]
avg
avg
avg

Substitute the values.

-202.21 [(x611)+(4xE(CH)(2x436)]-[8x415]
4xE (С-Н) 3 1634.79
C-H 408.70kJ/mol
avg
avg

Therefore, the average bond energy of С,Н,
is408.70kJ/ mol.

The given reaction is

>2CH,(g)
C2H2(g)+3H(g)
|AH 376.74kJ/mol

Average bond energy in

Number ofbond in 3 molН, %33

Average C C
bond energy in C2H2 835kJ/mol

Number ofC C
bond in 1 molС,Н, -1

Number ofbond in 1 molC,H2 2

Calculate the average bond energy of the reaction.

bondenergy of reactant - >bond energy of product
AH
reaction
=I(1xE(C C)+(2XEA(C-H)+(3xE (H-H)]-[8xEC-H)]
avg
avg
avg
avg

Substitute the values.

-376.74 [(x835)+(2x E(CH)+(3x436)]-[8x415]
|2xEv (CH) 800.26
avg
avg
C-H 400.13KJ /mol

Therefore, the average bond energy of С,Н,
2
is400.13 kJ/ mol.

Ans:

Average C-H bond energy in ethane|411.98|kJ /mol
Average C-H bond energy in ethene|408.70 kJ/mol
Average C-H bond energy in e

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