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Hydrogen sulfide has a pKa of 7.05. If hydrocyanic acid has a pKa of 9.21 and...

Hydrogen sulfide has a pKa of 7.05. If hydrocyanic acid has a pKa of 9.21 and fluoroacetic acid has a pKa of 2.59, which one would act as a base in the presence of hydrogen sulfide instead of an acid?
A. Does the acid react with the lower pKa or the base?
B. Which of the two acids would act as a base in the presence of hydrogen sulfide and why?
C. Of the three acids mentioned, which one would form the most stable conjugate base?
D. If the acid forms the most stable conjugate base, does that make it the strongest it weakest and why?
E. In order to form the most stable conjugate base, does that make the acid more or less willing to donate its hydrogen?
F. Which of the three aids would for the most stable conjugate base and why?
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Answer #1

In the presence of hydrogen sulfide, hydrocyanic acid would act like a base instead of an acid.

A. No, as in the reaction of a weak acid, hydrogen sulfide with a weak base, hydrocyanic acid, the products formed will be the same on both sides of the reaction equation.

B. Hydrocyanic acid will at as base in presence of hydrogen sulfide because of the higher value of pKa of hydrocyanic acid than that of hydrogen sulfide.

*acid strength is inversely proportional to pKa value, i.e., strong acids have lower pKa value and weaker acid have higher pKa values.

C.  Of the three acids mentioned, the weakest acid (with the highest pKa value= 9.21), hydrocyanic acid forms the most stable conjugate base.

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