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Clayperon equation is used.
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Discussion Worksheet Tuesday, June 4h . Tin undergoes the following reaction: Sn(s, gray) = Sn(s,white). This...
One mole of H20( is supercooled to-5.00°C at 1 bar pressure before freezing at that temperature....
One mole of H20( is supercooled to-5.00°C at 1 bar pressure before freezing at that temperature. Calculate ASys, ASum, and ASeotal for this process. Is it spontaneous? CPm (H20, 1)- 75.3 J/mol.K CPm (H20, s)-37.7 J/mol.K AHfusion 6.008 kJ/mol Hint: remember that ASs is computed using q along a reversible path, while ASur is computed using the actual heat transfer during the freezing. For the following equilibrium reaction: Here is an ICE table, starting from no moles of pure 0z...
The solid-state transition of Sn(gray) to Sn(white) is in equilibrium at 18.0 °C and 1.00 atm,...
The solid-state transition of Sn(gray) to Sn(white) is in equilibrium at 18.0 °C and 1.00 atm, with an entropy change of 8.8 J K-1 mol-1. The density of gray tin is 5.75 g cm-3; that of white tin is 7.28 g cm-3. Calculate the transition temperature at a pressure of 100.0 atm.
Using enthalpies of formation (Appendix C), calculate ΔH ° for the following reaction at 25°C. Also...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C....
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
One mole of H20( is supercooled to-5.00°C at 1 bar pressure before freezing at that temperature. Calculate ASys, ASum, and ASeotal for this process. Is it spontaneous? CPm (H20, 1)- 75.3 J/mol.K CPm (H20, s)-37.7 J/mol.K AHfusion 6.008 kJ/mol Hint: remember that ASs is computed using q along a reversible path, while ASur is computed using the actual heat transfer during the freezing. For the following equilibrium reaction: Here is an ICE table, starting from no moles of pure 0z...
The solid-state transition of Sn(gray) to Sn(white) is in equilibrium at 18.0 °C and 1.00 atm, with an entropy change of 8.8 J K-1 mol-1. The density of gray tin is 5.75 g cm-3; that of white tin is 7.28 g cm-3. Calculate the transition temperature at a pressure of 100.0 atm.
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
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