Question

What is the heat of combustion of ethane, C2H6, in kilojoules per mole of ethane? I...

What is the heat of combustion of ethane, C2H6, in kilojoules per mole of ethane?

I know the answer is -1560. I need to know WHY and HOW to get to this answer.

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Answer #1
Concepts and reason

Write the balanced equation for the combustion of ethane.

Calculate the value of heat of combustion by using the standard values of enthalpies of formation of reactants and products.

Fundamentals

A balanced equation is an equation which contains all the reactants and products in a fixed ratio. A balanced equation has the following characteristics:

1. It should follow the law of conservation of mass.

2. The total number of different types of elements on reactant side should be equal to the product side.

3. Stoichiometric coefficients are put in front of the molecules on both the reactant and product side to balance a given reaction. The coefficients to be used are whole number or fractional number.

Combustion is a chemical process in which the substance is burned in the presence of oxygen. The products formed are called combustion products.

The amount of heat released on combustion of a substance is called the heat of combustion of that substance. It is denoted by . The unit of heat of combustion is kJ/mol
.

The combustion reaction of ethane is written as follows:

C,H, +0, → CO, +H,0

Add a coefficient of (7/2) for , a coefficient of 2 for and a coefficient of 3 forto get the balanced equation.

The balanced reaction is written as follows:

CH. + 0, -> 200, +34,0

The balanced reaction for the combustion of ethane is written as follows:

The enthalpy of the above reaction is the heat of combustion of ethane.

The standard enthalpy of formation are as follows:

AHCM. = -84.7 kJ/mol
AH., = 0kJ/mol
AH 1,0 =-285.8kJ/mol
AHCO = -393.5 kJ/mol

The enthalpy of the above reaction is calculated as follows:

A#° = AH |-- AHME
=(2(246o.)+3(x114,)-(artén. +3(46.))
=(26-393.5 kJ / mol) +3(-285.8kJ/mol)-(-84.7kJ/mol+? (0)
=-1559.7 kJ/m

Ans:

The heat of combustion of ethane, , per mole of ethane is -1559.7 kJ/mol
.

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