2. (2 points) Draw the products obtained from the S2 reaction of (show reaction mechanism) a....
Draw the SN2 mechanism of the reaction between (S)-2-bromobutane
and iodid ion. Show lone pairs, electron pushing arrows, 3-D view
to reflect appropriate stereochemistry, reactants, transition
states, and products. name the product. draw and completely label a
reaction energy diagram corresponding to the mechanism you have
drawn.
f. Draw the Sn2 mechanism of the reaction between (s)-2-bromobutane and iodide ion. Show lone pairs, electron pushing arrows, 3-D view to reflect appropriate stereochemistry, reactants, transition states, and products. Name the product....
Draw the structural formula for the reagents and the products for the following reactions. Watch the stereochemistry where appropriate. Indicate the mechanism for each (E1, E2, SN1, SN2). The reaction of t-butylbromide with a strong base and heat. The reaction of R-2-bromobutane with methanol. The reaction of R-2-bromobutane with sodium methoxide in acetone. The reaction of R-2-bromobutane with sodium t-butoxide and heat. The reaction of 2-methyl-2-iodopentane with water.
02 Question (2 points) Draw a mechanism for the reaction of the ketone with hydronium ion. In the first box, draw any necessary curved arrows. Show the products of the reaction in the second box. Include any nonzero formal charges and all lone pairs of electrons. V 1st attempt See Periodic Table See Hint ISO i Draw any necessary curved arrows to show the reaction between the ketone and hydronium ion.
1. Using the reaction of 2-chloro-1-methylcyclohexane with hydroxide ion, give the mechanism of Sn1 substitution. Complete the question as in question 1 2. Show how you might synthesise the following compounds given the indicated starting materials and anything else you need. In other words, show the reactions that would lead from starting materials to products. Assume that you can purify the products of each reaction. A synthesis may require more than one reaction (products of one reaction are used as starting materials in the...
1.2.3.4.5.6.7.8.Show the curved arrow mechanism for the reaction between ethoxide and methanol to give ethanol and the methoxide ion. 1st attempt Jual See Periodic Table See Hint OH-Ö: Add the missing curved arrow notation.The carbon-metal bond in organometallic Grignard reagents exhibits significant covalent character. However, we can treat these compounds as electron-rich carbanions because of the large difference in electronegativity between carbon and magnesium. These reagents are great to form carbon-carbon bonds but must be kept in an anhydrous environment...
S2 reactions proceed through an inversion of stereochemistry. To illustrate this, show the mechanism, including the transition state of the reaction of methyl iodide with sodium cyanide. 5. For the following pairs indicate which is the stronger nucleophile and why you came to that conclusion 6 Water (H,O) Vs Sodium hydroxide (NaOH) a. b. Potassium lodide (K) vs Potassium Fluoride (KF) Sodium methoxide (NaOCH) Vs. Sodium tert-butoxide (NaOC(CH) 7. A. in an S1 reaction when you double the concentration of...
a) Draw all of the products obtained from the base-catalyzed aldol condensation reaction between butanal and pentanal(crossed and self) b) Show the half reaction corresponding to the reduction of permanganate ion to manganese dioxide. Show the half reaction corresponding to the oxidation of cyclopentene to 1,2 dihydroxycyclopentane. Add the two half-reactions together to give the overall net ionic equation of the oxidation of cyclopentene to 1,2 dihydroxycyclopentane using permanganate ion. Can anyone help me out?
2. Show the mechanism and product or products for an E2 reaction. (Mechanism 9.5 in your text walks you through this example). H3CX -CH3 CH CH OH н В a. What is the rate law for an E2 elimination reaction? How does it compare to the rate law for an S2 reaction? b. Do you think that both E2 and S2 reactions will have similar reaction energy diagrams? Why or why not?
Show the mechanism and all possible products for the following reaction. Be sure to include arrows and tell whether the reaction is SN2,E2 or SN1/E1. Label the anion as base or nucleophile, and determine whether you have a protic or aprotic solvent. 2-chlorohexane with sodium amide in DMSO 3-bromoheptane with sodium propoxide in propanol (2S)-2-chloro-3-ethyloctane with potassium butoxide (3R)-3-bromo-3-methylnonane with sodium cyanide
5. Mechanism: (20 pts) Show the detailed reaction mechanism including all relevant arrows, intermediates, inorganic products, relevant resonance structures, and stereochemistry for the following reaction. heat OH H-Br step 1 step 2 step 3 step 4 Product(s) a. This is a S2/Sx1/E/E2/ reduction / oxidation mechanism. b. What is the product if the starting alcohol is reacted with PBrz? Product(s) with PBrz c. Reaction with PBr3 is a S2/S1/Ej / E2 / reduction / oxidation mechanism.