3. (2 points) Provide a mechanism, using curved arrow notation, for the formation of glycine and...
Using the curved arrow notation, write a stepwise mechanism to rationalize the formation of each product in the following reaction (you may need the back of this sheet).
12 Question (2 points) @ See page 897 Draw the curved arrow mechanism for the formation of the major enamine product from the given iminium ion and amine. Draw all electrons and charges if necessary on the product; do not show any side products. V 1st attempt See Periodic Table D See Hint CH
3. Mechanism: Draw the curved arrow mechanism for the following hydrolysis reaction, only draw the mechanism from the starting material to the neutral functional group intermediate. Additionally, indicate what is in the final product by writing Y="appropriate atom here". Use only the reagents provided below, in your mechanism. (5 pts) excess NaOH H2O, heat HNĐ neutral functional group intermediate 9. Mechanism: Draw the curved arrow mechanism for the following reaction. Please be aware that during the mechanism you will form...
3. Draw the curved arrow mechanism for the formation of both products. If there is a shared intermediate you may redraw it to show formation of the second product.
3. Draw the curved arrow mechanism for the formation of both products. If there is a shared intermediate you may redraw it to show formation of the second product. HO
Predict the major substitution product(s) and provide a curved arrow mechanism for the formation of the product. H20 Draw the major product(s). Include stereochemistry in your answer. ? Edit Draw step 1. Loss of leaving group. Include lone pairs, formal charges and stereochemistry in your answer. ? Edit Draw step 2. Carbocation rearrangement. Include lone pairs, formal charges and stereochemistry in your answer. dy ? Edit Drawstep 3. Nucleophilic attack. Draw both enantiomers in products if any. Include one pairs,...
Provide an explicit mechanism using correct curved-arrow formalism for the formation of the product(s). Provide an explanation for the formation of the product(s), if multiple are present, why are both possible? What critical reactivity is required, and how is that reflected in the starting material(s) and intermediate/transition state?
• Use the curved-arrow notation to draw the mechanism for the formation of 2-methyl-2-hexanol from n-butylmagnesium bromide. • Discuss, using the mechanism, why it is important to use anhydrous diethyl ether in this reaction. • Describe how you would purify the final product by distillation. What obstacles would you run into?
4. Provide a complete curved-arrow mechanism for each of the following transformations involving conjugate addition Note that no stereochemistry is shown or implied in any of these reactions, and you may neglect it in your mechanisms as well. a. For this mechanism, you may assume that the reagent NaBH.CN behaves just like NaBHs, and that it preferentially performs 1,4-addition to unsaturated carbonyl compounds. O ! OME OMe H 1. NaOE, ETOH 2. NaBH CN, MOH oMe ОMe OME OME EtOXOE...
2. Predict the product CHE CH,SNa 3. Provide a curved-arrow mechanism, and explain the observed stereochemistry 1) NaOH(aq) (excess) 2) H' workup 4. Explain the difference in reactivity م - م . KOBU no reaction! 5. Explain the difference in reactivity conc. Heso no reaction!