Question

Organocuprates are organometallic reagents with th

Organocuprates are organometallic reagents with the general formula R2CuLi. Predict the organic coupling product in the following organocuprate reaction.

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Concepts and reason

Coupling Reactions:

The coupling reaction in organic chemistry involves the joining of two organic molecular (hydrocarbon) fragments such as alkyl (R) through the carbon-carbon sigma bonds with the help of organometallic reagents such as the organocuprates.

Fundamentals

Gilman Reagents (R_Culi
):

Gilman reagent is an organometallic reagent that acts as a nucleophile in the bimolecular nucleophilic substitution () reaction.

Structure:

Li
Cu
R
R

The nucleophile and the electrophile in the given reaction are:

Lit
Nucleophile

Electrophile

Mecahnism not known fully
SN2
[ + 3d

Ans:

The organic coupling product in the given organocuprate reaction is:

W

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