Question

In each reaction box, place the best reagent and conditions from the list below. (Some reagents...

In each reaction box, place the best reagent and c

In each reaction box, place the best reagent and conditions from the list below. (Some reagents may be used more than once.)

0 0
Add a comment Improve this question Transcribed image text
Answer #1
Concepts and reason

The concept used to solve this problem is by using the given reagents, possible products will be formed in each step and then label it exactly in the given boxes in order to form the exact product.

Here, the starting reactant is propylene and the final product is epoxide.

Fundamentals

Sodium hydride ( NaH{\rm{NaH}} ) is used as base, which abstract the proton.

Hydroboration in the presence of tetrahydrofuran followed by the oxidation gives a primary alcohol.

Addition of Br2andH2O{\rm{B}}{{\rm{r}}_2}\;{\rm{and}}\;{{\rm{H}}_2}{\rm{O}} to the double bond forms a halohydrin product.

Sodium borohydride is used as a reducing agent for the conversion of aldehyde to primary alcohol and ketone to secondary alcohol.

Reduction of alkyne with H2{{\rm{H}}_2} in the presence of Lindlar’s catalyst gives cis alkene. Similarly, the trans alkene is formed with Na{\rm{Na}} in the presence of NH3(l){\rm{N}}{{\rm{H}}_3}\left( l \right) .

The reaction is as follows:

е
NaH
Нас —с с—н
-Нас—сС:
prop-1-yn-1-ide
prop-1-yne

The reaction is as follows:

CH3CH2Br
Нас — сс:
Hас — с—с— сH2—сHз
prop-1-yn-1-ide
pent-2-yne

The reaction is as follows:

H
Н
H2, Lindlars catalyst
Hас—
ЕC—СH2—СH3
pent-2-yne
Hэс
CH2—CHЗ
(Z)-pent-2-ene

The reaction is as follows:

ОН
н
H Br
H
H
C C
Н-0
CHа—CH
Br
Нас
CHа—CHз
ОН
Нас
CH2 CH3
Hас
(Z)-pent-2-ene
(2R,3R)-2-bromopentan-3-ol
(2R,3R)-3-bromopenta

The reaction is as follows:

н он
Br
H
+
CHа—CHз
Br
Hас
CHa—CHз
ОН
Hас
(2R,3R)-2-bromopentan-3-ol
(2R,3R)-3-bromopentan-2-ol
NaH
Х. Ж.
+
Hас
CH— CHз
НэС
C

Ans:

The best reagents that are used in this reaction are as follows:

NaH
1)
2)
CH3CH2Br
+
Нзс—с—с—н
3)
H2, Lindlars Catalyst
-CHз
Нас
CH3
Нас
4)
Brр, НаО
5)
NaH

Add a comment
Know the answer?
Add Answer to:
In each reaction box, place the best reagent and conditions from the list below. (Some reagents...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT