Activation of the ring towards substitution :
-NHCOCH3, -OCOCH3,
Withadrawl of electrons through resonance :
-COOH, -CN
Ortho/Para directed substitution :
-NHCOCH3, -F , -CH3, -Br
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can...
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring. Substituents on an aromatic ring...
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring Activation of the ring towards...
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as XY, where X is the atom directly bound to the aromatic ring. Activation of the ring towards...
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring. Activation of the ring towards...
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring.
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring. Activation of the ring towards substitution. Withdrawal of electrons through...
Synthesis of disubstituted benzenes involves two steps, each introducing one of the functional groups For the synthesis of p-chlorosulfonic acid, select the reagent for each step and draw the structure of the monosubstituted intermediate compound. Put the intermediate substituent in the same place that it is oberved in the product (i.e. either the top or the bottom of the benzene ring). Intermediate Step 1 Step 2 O C2, peroxide O Ch. FeCl3 O SOs, H2S04 O Cl2. peroxide O Cl2....
1. (0.3pts) Identify the most reactive site(s) on the substituted arenes below toward electrophilic aromatic substitution SO, NO2 2. (0.7pts) For each functional group, identify the description that best matches the group's substituent effects. Some of the statements below will require more than one answer to be fully correct. CO" -OH + Br -CH2CH3 collon të na pécon tim a. Donates electrons by hyperconjugation and does not donat lectrons by resonar BO b. Withdraws electrons inductively and withdraw c. Deactivates...
Activating/Deactivating Substituents Below is a list of different substituents and experimental results from attempted electrophilic aromatic substitution. PhNR, PHCN PhCHO PhF PhMe PhoMe PhNH Deactivating Activating PhNO, PhSozH Phl PhH PNHAC POH • Is the aromatic ring an [ electrophile / nucleophile ] in these reactions? Which substituents 'activate the ring (i.e. make it more reactive? 0 Alkyl substituents: Activate OR Deactivate o Halide substituents: Activate OR Deactivate o OH, NH substituents: Activate OR Deactivate o carbonyl groups: Activate OR...
Nitration of phenols is a classic example of an electrophilic aromatic substitution reaction. a) Why does the nitration of phenol (hydroxybenzene) proceed only in the ortho- and para-positions on the ring? b) Draw the resonance structures that highlight the ortho- and para-directing nature of hydroxy substituents. Make sure to include the structures that showcase the movement of the charges in the ring.