What is a nitrenium ligand? How does it compare with an N -heterocyclic carbene? Which of these types of ligand is viewed as a stronger sigma donor, and what experimental evidence supports this view? What role do pincer ligands play in nitrenium complexes? (See Y. Tulchinsky, M. A. Iron, M. Botoshansky, M. Gandelman, Nature Chem. , 2011 , 3 , 525.)
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