Cation 1 reacts with the ion , a potential source of hydride, to form 2 . The following data are reported for 2 :
IR: strong bands at 1920, 1857 cm-1 . 1H NMR : chemical shift (relative area):
5.46 (2)
5.28 (5)
5.15 (3)
4.22 (2)
1.31 (27)
In addition, a small peak is believed to be hidden under other peaks. 13C NMR : resonance at 236.9 ppm, seven additional peaks and clusters of peaks between 32.4 and 115.7 ppm. Propose a structure for 2 , and account for as much of the experimental data as possible. (See I. Amor, D. García- Vivó, M. E. García, M. A. Ruiz, D. Sáez, H. Hamidov, J. C. Jeffery, Organometallics , 2007 , 26 , 466.)
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