Problem

The equilibrium constants for the ligand dissociation reaction have been determined for...

The equilibrium constants for the ligand dissociation reaction have been determined for a variety of phosphines. (See C. A. Tolman, W. C. Seidel, L. W. Gosser, J. Am. Chem. Soc. , 1974 , 96 , 53). For L = PMe3, PEt3, PMePh2, and PPh3, arrange these equilibria in order of the expected magnitudes of their equilibrium constants (from largest K to smallest).

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Solutions For Problems in Chapter 14