Problem

The compound [Ru(CO)6][Sb2F11]2 has a strong infrared band at 2199 cm-1. The spectrum of...

The compound [Ru(CO)6][Sb2F11]2 has a strong infrared band at 2199 cm-1. The spectrum of [Ru(13CO)6][Sb2F11]2 has also been reported. Would you expect the band observed at 2199 cm-1 for the 12C compound to be shifted to higher or lower energy for the analogous 13C compound? (See C. Wang, B. Bley, G. Balzer-Jollenbeck, A. R. Lewis, S. C. Siu, H. Willner, F. Aubke, Chem. Commun. , 1995 , 2071.)

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