Problem

a. Account for the following trend in IR frequencies: b. The ion [RuCl(NO)2...

a. Account for the following trend in IR frequencies:

b. The ion [RuCl(NO)2(PPh3)2]+ has N – O stretching bands at 1687 and 1845 cm-1. The C – O stretching bands of dicarbonyl complexes typically are much closer in energy. Explain.

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