Problem

On the basis of the 18-electron rule, identify the first-row transition metal for each o...

On the basis of the 18-electron rule, identify the first-row transition metal for each of the following:

a. [M(CO)7]+

b. H3CM(CO)5

c. M(CO)2(CS)(PPh3)Br

d. [(h3-C3H3)(h5-C5H5)M(CO)]-

(has linearly coordinated NO)

h. [M(CO)4I(diphos)]- (diphos = 1,2-bis(diphenylphosphino)ethane)

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