Problem

Both positive and negative-ion ESI mass spectra of IMe4Sb][Ph2SbCl4] were recorded. In one...

Both positive and negative-ion ESI mass spectra of IMe4Sb][Ph2SbCl4] were recorded. In one spectrum, [Data: C. Nunez et al. (2009) Inorg. Chim. Acta, vol. 362, p. 3454.]

(6.4%), 417 (100%), 418 (13.1%), 419 (78.6%), 420 (10.2%), 421 (30.1%), 422 (3.9%) and 423 (5.7%).

(a) Account for the results, stating which mass spectrum was recorded in positive and which in negative mode,

(b) Draw the structures of the ions present in [Me4Sb][Ph2SbCl4]. Does either of the ions possess isomers? If so, do the mass spectrometric data provide information about which isomer or isomers are present? (Isotopes: see Appendix 5.) |Data: H..1. Breunig et al. (2010) .. Organomet. Chem., vol. 695, p. 1307.]

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