MeCN solutions of NbCL5 and HF contain a mixture of octahedral [NbF6]–, [NbF5Cl]–, [NbF4Cl2]–, [NbF3Cl3]–and [NbF2Cl4]–. Predict the number and coupling patterns of the signals in the 19F NMR spectrum of each separate component in this mixture, taking into account possible isomers. (Assume static structures and no coupling to 193Nb.)
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