Problem

The first-order irreversible exothermic liquid-phase reactionA→ Bis to be carried out in a...

The first-order irreversible exothermic liquid-phase reaction

A→ B

is to be carried out in a jacketed CSTR. Species A and an inert I are fed to the reactor in equimolar amounts. The molar feed rate of A is 80 mol/min.

(a) What is the reactor temperature for a feed temperature of 450 K?

(b) Plot the reactor temperature as a function of the feed temperature.

(c) To what inlet temperature must the fluid be preheated for the reactor to operate at a high conversion? What are the corresponding temperature and conversion of the fluid in the CSTR at this inlet temperature?

(d) Suppose that the fluid is now heated 5 °C above the temperature in part (c) and then cooled 20 °C, where it remains. What will be the conversion?

(e) What is the inlet extinction temperature for this reaction system?

Additional information:

Heat capacity of the inert: 30 cal/g mol -°C τ = 100 inin

Heat capacity of A and B: 20 cal/g mol -°C ΔH°Rx = −7500 cal/mol

UA \ 8000 cal/min-°C k = 6.6 X 10−3 min−1‘at 350 K

Ambient temperature, Ta: 300 K E = 40,000 cal/mol • K

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Solutions For Problems in Chapter 8