Rate Laws (Section)
The iodide ion reacts with hypochlorite ion (the active ingredient in chlorine bleaches) in the following way: OCl- + I - .OI- + Cl- . This rapid reaction gives the following rate data:
[OCl_] (M) | [I_] (M) | Initial Rate (M/s) |
1.5 × 10-3 | 1.5 × 10-3 | 1.36 × 10-4 |
3.0 × 10-3 | 1.5 × 10-3 | 2.72 × 10-4 |
1.5 × 10-3 | 3.0 × 10-3 | 2.72 × 10-4 |
(a) Write the rate law for this reaction.
(b) Calculate the rate constant with proper units.
(c) Calculate the rate when [OCl-] = 2.0 × 10-3 M and [I -] = 5.0 × 10-4 M.
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