Problem

The following mechanism has been proposed for the gasphase reaction of chloroform (CHCl3)...

The following mechanism has been proposed for the gasphase reaction of chloroform (CHCl3) and chlorine:

(a) What is the overall reaction? (b) What are the intermediates in the mechanism? (c) What is the molecularity of each of the elementary reactions? (d) What is the ratedetermining step? (e) What is the rate law predicted by this mechanism? (Hint: The overall reaction order is not an integer.)

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Solutions For Problems in Chapter 14

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