Calculate the lattice energies of the hypothetical compounds NaCl2 and MgCl, assuming that the Mg+ and Na+ ions and the Na2+ and Mg2+ ions have the same radii. How do these results explain the compounds that are found experimentally?
Use the following data in the calculation: Second ionization energies Na, 4562 kJ/mol; Mg,1451 J/mol; enthalpy of formation: NaCl, –411 kJ/mol;
MgCl2, –642 kJ/mol.
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