The superconductivity of a binary barium germanide, BaGe3 , has been established (H. Fukuoka, Y. Tomomitsu, K. Inumaru, Inorg. Chem. , 2011 , 50 , 6372). What data were used to determine that BaGe3 was metallic, and what observation prompted the assignment of the 4.0 K critical temperature? Density of states (DOS) calculations help assess orbital contributions to superconductor band structure. Which orbitals contribute the most to the conduction band of BaGe3 ? Which orbitals contribute most near the BaGe3 Fermi level?
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