For solid Ba[CSc3], the vibrational wavcnumbers and assignments for the [CSe3]2- ion are 8O2 (£", stretch), 420 (A2290 (/!,’) and 185 (F, deformation) cm-1.
(a) Based on these assignments, deduce the shape of the [CSe3J2- ion.
(b) (b) Draw diagrams to illustrate the modes of vibration of [CSe3]2-.
(c) (c) Which modes of vibration are IR active?
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