Problem

Comment on each of the following observations.(a)   The carbides Mg2C3 and CaC? liberate p...

Comment on each of the following observations.

(a)   The carbides Mg2C3 and CaC? liberate propyne and ethyne respectively when treated with water, reaction between ThC2 and water produces mixtures composed mainly of C?FI?, C2PI6 and H2, but no reaction occurs when water is added to TiC.


(b)  Mg?Si reacts with [NH4]Br in liquid NH3 to give silane.


(c)  Compound 14.43 is hydrolysed by aqueous alkali at the same rate as the corresponding Si—D compound.

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Solutions For Problems in Chapter 14