The integrated rate law for the zeroth-order reaction A → B is [A]t = [A]0 − kt. (a) Sketch the following plots: (i) rate versus [A]t and (ii) [A]t versus t. (b) Derive an expression for the half-life of the reaction. (c) Calculate the time in half-lives when the integrated rate law is no longer valid, that is, when [A]t = 0.
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