A protein molecule P of molar mass dimerizes when it is allowed to stand in solution at room temperature. A plausible mechanism is that the protein molecule is first denatured (that is, loses its activity due to a change in overall structure) before it dimerizes:
where the asterisk denotes a denatured protein molecule. Derive an expression for the average molar mass (of P and P2), , in terms of the initial protein concentration [P]0 and the concentration at time t, [P]t, and . Describe how you would determine k from molar mass measurements.
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