The molar solubility of AgCl in 6.5 × 10−3 M AgNO3 is 2.5 × 10−8 M. In deriving Ksp from these data, which of the following assumptions are reasonable? (a) Ksp is the same as solubility, (b) Ksp of AgCl is the same in 6.5 × 10−3 M AgNO3 as in pure water, (c) Solubility of AgCl is independent of the concentration of AgNO3. (d) [Ag+] in solution does not change significantly upon the addition of AgCl to 6.5 × 10−3 M AgNO3. (e) [Ag+] in solution after the addition of AgCl to 6.5 × 10−3 M AgNO3 is the same as it would be in pure water.
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