For the following reaction at 600. K, the equilibrium constant, Kp, is 11.5.
PCl5(g) PCl3(g) + Cl2(g)
Suppose that 2.210 g of PCl5 is placed in an evacuated 535 mL bulb, which is then heated to 600. K.
(a)
What would be the pressure of PCl5 if it did not dissociate?
(b)
What is the partial pressure of PCl5 at equilibrium?
(c)
What is the total pressure in the bulb at equilibrium?
(d)
What is the degree of dissociation of PCl5 at equilibrium?
For the following reaction at 600. K, the equilibrium constant, Kp, is 11.5. PCl5(g) PCl3(g) + Cl2(g) Suppose that 2.21...
The following reaction has equilibrium constant of Kp = 11.5 atm at 300 oC: PCl5(g) PCl3 (g) + Cl2 (g). A flask was charged with pure PCl5 (g) and allowed to achieve the equilibrium, at which partial pressure of PCl5 (g) was 1.50 atm. Find (a) total pressure at equilibrium (b) partial pressures of PCl3 (g) and Cl2(g), (c) initial pressure of PCl5.
At 500 K the reaction PCl5(g) <----> PCl3(g) + Cl2(g) has Kp = 0.497. In an equilibrium mixture at 500 K, the partial pressure of PCl5 is 0.860 atm and that of PCl3 is 0.350 atm. What is the partial pressure of Cl2 in the equilibrium mixture?
1. The equilibrium constant, Kp, for the following reaction is 0.497 at 500 K: PCl5(g) <----> PCl3(g) + Cl2(g) Calculate the equilibrium partial pressures of all species when PCl5(g) is introduced into an evacuated flask at a pressure of 1.00 atm at 500 K. PPCl5 = atm PPCl3 = atm PCl2 = atm 2. The equilibrium constant, Kp, for the following reaction is 0.215 at 673 K: NH4I(s) <----> NH3(g) + HI(g) Calculate the equilibrium partial pressure of HI when...
The equilibrium constant (Kp) for the interconversion of PCl5 and PCl3 is 0.0121 at certain temperature. A vessel is charged with PCl5 giving an initial pressure of 0.123 atm. PCl5 (g) ⥦ PCl3 (g) + Cl2 (g) a) Calculate equilibrium partial pressure of PCl3 b) Calculate total pressure at equilibrium
The equilibrium constant Kp for the reaction PCl5(g) <---> PCl3(g) + Cl2(g) is 1.15 at 25 degrees Celsius. The reaction starts with a mixture of 0.177 atm PCl5, 0.223 atm PCl3, and 0.111 atm Cl2. When this mixture comes to equilibrium at 25 degrees Celsius, what are the equilibrium pressures of each component?
For the following reaction, Keq is 0.00183 at 390. K: PCl5(g) PCl3(g) + Cl2(g) If 3.72 g of PCl5 is placed in a 3.68 L bulb at 390. K, what is the equilibrium pressure of Cl2? 1 atm = 1.013 bar bar The number of significant digits is set to 3; the tolerance is +/-4%
The equilibrium constant for the following reaction is 1.42×10-3 at 179 °C. PCl5(g)<-->PCl3(g) + Cl2(g) K = 1.42×10-3 at 179 °C Calculate the equilibrium constant for the following reactions at 179 °C. (a) PCl3(g) + Cl2(g)<--> PCl5(g) K = (b) 2 PCl5(g)<-->2 PCl3(g) + 2 Cl2(g) K =
Phosgene can dissociate into carbon monoxide and chlorine COC2g)CO Cl2(g) At 600 °C, the equilibrium constant in terms of pressures, Kp, for this dissociation reaction is 5.00. (a) If 11.56 g of phosgene is placed in a 17.60-L vessel and heated to 600 °C, what is the partial pressure of carbon monoxide when equilibrium is attained? atm (b) What fraction of phosgene is dissociated at equilibrium?
The equilibrium PCl5(g) ⇄ PCl3(g) + Cl2(g) is established at 250oC. At equilibrium the partial pressures of the components are 0.020 Atm (PCl5), 1.28 Atm (PCl3), and 1.28 Atm (Cl2). If the partial pressure of Cl2 is suddenly increased to 2.15 Atm, what is the partial pressure of PCl5 after equilibrium has been reestablished?
The equilibrium constant, K, for the following reaction is 2.35×10-2 at 517 K. PCl5(g) PCl3(g) + Cl2(g) An equilibrium mixture of the three gases in a 11.3 L container at 517 K contains 0.269 M PCl5, 7.94×10-2 M PCl3 and 7.94×10-2 M Cl2. What will be the concentrations of the three gases once equilibrium has been reestablished, if the equilibrium mixture is compressed at constant temperature to a volume of 5.27 L? [PCl5] = M [PCl3] = M [Cl2] =...