Predict the oxidation product of treating the given alkene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H\'s on chirality centers. (mCPBA = meta-chloroperoxybenzoic acid)
The concept used to solve this problem is epoxidation of the double bond using meta chloro perbenzoic acid followed by the reaction with acid.
Epoxidation is the addition of single oxygen atom the double bond.
Under acidic conditions, the nucleophile preferentially attacks the more substituted ring carbon.
Under basic or neutral conditions, the nucleophile preferentially attacks at the less substituted (or less sterically hindered ring carbon).
The reaction is as follows:
The reaction is as follows:
Ans:The oxidation product is as follows:
Predict the oxidation product of treating the given alkene with the reagents shown below. Only draw one enantiomer if...
Predict the oxidation product of treating the given alkene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H\'s on chirality centers. (mCPBA = meta-chloroperoxybenzoic acid)
Predict the oxidation product of treating dihydro naphthalene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H's on chirality centers. (mCPBA = meta-chloroperoxybenzoic acid) (1) mCPBA, CH2CL2----------------------->dihydro naphthalene (2) H+, H2O
Predict the oxidation product of treating the given alkene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H's on chirality centers.
Predict the oxidation product of treating the given alkene with reagents shown below. only draw one enantiomer if more than one is possible. Include H's on chirality centers. (THF=tetrahydrofuran)
Predict the oxidation product of treating dihydronaphthalene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H's onchirality centers. (mCPBA= meta-chloroperoxybenzoic acid)
1. Predict the oxidation product of treating the given alkene with the reagents shown below. For any generated stereocenter specify the configuration via wedge ans dash bondsd, only draw on enantiomer if more than one is possible, include Hydrogen bonds on chirality center 2. Predict the oxidation product of treating the given alkene with the reagents shown below. For any generated stereocenter specify the configuration via wedge ans dash bondsd, only draw on enantiomer if more than one is possible,...
Predict the oxidation product of treating dihydronaphthalene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H's on chirality centers. Assume only one of the double bonds shown will react. Which one will it be? (A stability-reactivity principle will apply.) 4 dihydronaphthalene
Predict the oxidation product of treating the given alkene with the reagent shown below. Include stereochemistry where applicable. Include H's on chirality centers. (mCPBA = mefa-chloroperoxybenzoic acid)
Predict the reaction product of treating the given alkene with the reagent shown below. Only draw one enantiomer if more than one is possible. Include H's on chirality centers.
Predict in oxidation product of treating the given alkene with the reagents shown below For any generated. specify the configuration via wedge and dash bonds, only draw one more than one Is possible Include H's on centers. (THF = )