Daily Problem #38 Use a Born-Haber cycle to calculate the heat of the following reaction (AH/...
Using the thermodynamic quantities shown below: construct a
Born-Haber cycle for the following reaction: Li(s) + 1/2
F2(g)
LiF(s); calculate the lattice energy of LiF.
Vaporization of Li(s): +159
F2 bond enthalpy: +155
Li ionization energy: +520
F- electron affinity: +328
LiF(s) heat of formation: -616
4) Calculate the lattice enthalpy for calcium fluoride using the Born-Haber cycle method, using the provided table. (Show all your work; 2 points) Enthalpies, AH/(kJ mol) +192 Process Sublimation of Ca(s) Ionization of Ca(g) Dissociation of F2(g) Electron gain by F(g) Formation of CaF (s) +1735 to Ca(ag +157 -328 -1220
7. Use the Born Haber cycle and the given information to determine the net energy change (in kJ/mol) that takes place in the formation of KF(s) from the elements: Ks) + F2@KFS) Heat of sublimation of K = 89.2 kJ/mol Bond dissociation energy for F2 = 158 kJ/mol Lattice Energy of KF = 821 kJ/mol Eca for F = -328 kJ/mol E; for K = 418.8 kJ/mol
Draw the Born-Haber Cycle with these values and calculate
lattice energy.
Problem 1: Label each reaction listed below for the Born-Haber cycle in the formation of Cao lattice and calculate the lattice energy of Cal given the following information. AH KD) Ca(s) + Ca(8) 193 Calg) - Cat (8) + e 590 Cat (8) - Cat (8) + e- 2 O(g) + O2(g) O(8) + e- O (8) -141 O (8) + e- O (8) 878 Ca(s) + O2(g) →...
Use the Born-Haber Cycle and information given below to determine the lattice energy of LiF. Li(s) → Li(g) +159.3 kJ Li(g) → Li+(g) + e– +500.9 kJ F2(g) → 2 F(g) +158.8 kJ F(g) + e– → F–(g) –332.6 kJ Li+(g) + F–(g) → LiF(s) ? --------------------------------------------------- Li(s) + ½ F2(g) → LiF(s) – 616.0 kJ Group of answer choices +209.0 kJ –1023 kJ +1023 kJ –209.0 kJ –1102.4 kJ
2) From the following data in the Born-Haber cycle, Na(s) → Na(g) 4C12(g) → Cl(g) AH:-108 kJ/mol AHj - 495.9 kJ/mol ara =-349 kJ/mol Na(g) → Na+(g) + e- Cl(g) + e-→ Cl-(g) Na(s) +4C12(g) → NaCl(s) AHoverall =-411 kJ/mol calculate the lattice energy of NaCI.
Part I. Use a Born-Haber cycle to calculate the lattice energy of KCl from the following data. (5 marks) Ionization energy of K(g) = 444.0 kJ mol-1 Electron Affinity of Cl(g) = -381.0 kJ mol-1 Energy to Sublime K(s) = 152.0 kJ mol-1 Bond energy of Cl2 = 201.0 kJ mol-1 ∆rH for K(s) + 1/2 Cl2(g) ↔ KCl(s) = -480.0 kJ mol-1 art II. Using the lattice energy calculated in part I determine the enthalpy of solution potassium chloride...
Question 4 4 pts Use the Born-Haber Cycle to calculate the lattice energy for the formation of X2Y. Input your answer in units of kJ/mole with the correct sign. Process Enthalpy (kJ/mol). X(s)--> X(g) 115 X(g) -->X*(8) + le 499 Y2 (8) --> 2Y (8) 264 -295 Y (8) + 1e.-->Y (8) Y (8) + 1e' --> Y2 () 115 2X(s) +% Y2 (8)--> X2Y(s) -549
OADVANCED MATERIAL Interpreting a Born-Haber cycle This thermodynamic cycle describes the formation of an ionic compound M X2 from a metal element M and nonmetal element X in their standard states. Use it to answer the questions in the table below. 2+ 1100 1000 900 2- 800--- 700 600 M (8)+2X) 500. enthalpy 400 (kJ/mol) 300. M (g) + X, (g) 200 ▼ | 700,- 600 M (g) + 2x (g 500 enthalpy 400. 300. м (е) + x, (g)...
Part A Use the Born-Haber cycle, data from Appendix llBand the following table to calculate the lattice energy of Cao. (AsubH for calcium is 178 kJ/mol: EA 141 kJ/mol, EA 744 kJ/mol: IEC 590 kJ/mol. IE2 1145 kJ/mol. TABLE 9.1 Average Bond Energies Bond Energy Bond Energy Bond Energy Bond kJ mo 1) Bond (kJ mol 1) Bond (kJ mol 237 414 418 218 389 946 193 464 208 H 0 N-0 222 590 565 272 51 200 H-Br 364...