OADVANCED MATERIAL Interpreting a Born-Haber cycle This thermodynamic cycle describes the formati...
j This thermodynamic cycle describes the formation of an ionic compound M X from a metal element M and nonmetal element X in their standard states. Use it to answer the questions in the table below. 900. 2m* () + 2e + x (8) 800. 700. 600. 2M* (x) + x2 (g) 500. 400. 2M (8) + x() enthalpy (kJ/mol 24 (2) + 5x (2) 2M(5) + -,() 1 -100 - 200. M.X(s) What is the lattice enthalpy of M2X...
This thermodynamic cycle describes the formation of an ionic compound MX from a metal element M and nonmetal element X in their standard states. Use it to answer the questions in the table below 900 800 700 600 + X enthalpy 400 300. 200. 100. 0. 100.- kJ/mol M3 What is the lattice enthalpy of MX? 1 kJ/mol What is the enthalpy of formation of MX?kJ/mol Suppose both the heat of sublimation of M and the electron affinity of X...
Question 4 4 pts Use the Born-Haber Cycle to calculate the lattice energy for the formation of X2Y. Input your answer in units of kJ/mole with the correct sign. Process Enthalpy (kJ/mol). X(s)--> X(g) 115 X(g) -->X*(8) + le 499 Y2 (8) --> 2Y (8) 264 -295 Y (8) + 1e.-->Y (8) Y (8) + 1e' --> Y2 () 115 2X(s) +% Y2 (8)--> X2Y(s) -549
Using the Born Haber cycle in the previous question, and the following energies, calculate the standard energy of formation for Srl2 Enthalpy of sublimation of Sr(s) = 164 kJ/mol 1st ionization energy of Sr(g) = 549 kJ/mol 2nd ionization energy of Sr(g) - 1064 kJ/mol Enthalpy of sublimation of 12(s) = 62 kJ/mol Bond dissociation energy of 12(g) - 153 kJ/mol 1st electron affinity of l(g) = -295 kJ/mol Lattice energy of Srlz(s) = -1960 kJ/mol *Note: Do not include...
4) Calculate the lattice enthalpy for calcium fluoride using the Born-Haber cycle method, using the provided table. (Show all your work; 2 points) Enthalpies, AH/(kJ mol) +192 Process Sublimation of Ca(s) Ionization of Ca(g) Dissociation of F2(g) Electron gain by F(g) Formation of CaF (s) +1735 to Ca(ag +157 -328 -1220
Physical Chemistry: Use a Born-Haber cycle to find an experimentally based value for the lattice enthalpy of sodium bromide (NaBr(s)). The lattice enthalpy corresponds to the enthalpy change for the process NaBr(s) rightarrow Na^+(g) + Br^-(g) Use the following information in doing this problem. delta H degree_f(Na(g)) = 107.32 kJ/mol delta H degree_IE1(Na(g)) = 495.8 kJ/mol delta H degree_f(Br(g)) = 111.88 kJ/mol delta H degree_EA(Br(g)) = -324.6 kJ/mol delta H degree_f(NaBr(s)) = -361.06 kJ/mol The ionization enthalpy (IE_1) and electron...
Born-Fajans-Haber Cycle Suppose a chemist discovers a new metallic element and names it "Xtrinsium" (Xt) Xt exhibits chemical behaviour similar to an alkaline earth Xt(s) + Cl2(g) → XtCl2(s) Lattice energy for XtCl2 First Ionization energy of Xt Second Ionization energy of Xt Electron affinity of Cl Bond energy of Cl2 Enthalpy of sublimation (atomization) of Xt 2260. kJ/mol 430. kJ/mol 731 kJ/mol -348.7 kJ/mol 239 kJ/mol 170. kJ/mol Use the above data to calculate ΔHof for Xtrinsium chloride.
Using the thermodynamic quantities shown below: construct a Born-Haber cycle for the following reaction: Li(s) + 1/2 F2(g) LiF(s); calculate the lattice energy of LiF. Vaporization of Li(s): +159 F2 bond enthalpy: +155 Li ionization energy: +520 F- electron affinity: +328 LiF(s) heat of formation: -616
7. Use the Born Haber cycle and the given information to determine the net energy change (in kJ/mol) that takes place in the formation of KF(s) from the elements: Ks) + F2@KFS) Heat of sublimation of K = 89.2 kJ/mol Bond dissociation energy for F2 = 158 kJ/mol Lattice Energy of KF = 821 kJ/mol Eca for F = -328 kJ/mol E; for K = 418.8 kJ/mol
2) Write down a Born-Haber cycle for magnesium oxide (Mg0). Using the data provided below, determine the experimental value of the lattice enthalpy Uexp. Now calculate the lattice enthalpy Ucale (unit cell of Mg0 shown below). What do these values tell you about the bonding in Mg0? AHP(Mg0)--602 k]/mol Alto (Mg) = + 148 kJ/mol AH to (02) = +249 kJ/mol bond enthalpy (02)+498 k]/mol 16, (Mg) = +738 kJ/mol IE2 (Mg) +1451 k]/mol EA (O) = +142 kJ/mol EA2(0)...