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25. Carbon dioxide can be formed using two different isotopes of carbon: 12CO2 and 1CO2. a. Calculate the relative rates of
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Answer #1

(25.a)

We know that, Grahm's law of diffusion,

rate ∝ 1/√M

where,

M = Molar Mass

r12CO2/r13CO2 = √(45/44)

r12CO2/r13CO2 = 1.011

(25.b)

As rate of diffusion is inversaly proportional to molar mass.

Hence, lighter molecule 12CO2 diffuse at faster rate.

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