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3) Draw the mechanism for the following reaction. (6 pes) N-N OMSO The following total synthesis...
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for...
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: OH H3C- ??? + CH3 OH X steps Propose...
^ the top has been answered already Consider the following reaction: OH Н4С H,SO CH3 +...
^ the top has been answered already
Consider the following reaction: OH Н4С H,SO CH3 + ОН A Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: ОН. HzC...
6. Using either malonic ester synthesis or acetoacetic ester synthesis, outline a reaction scheme in each...
6. Using either malonic ester synthesis or acetoacetic ester synthesis, outline a reaction scheme in each case to show how you will synthesize compounds A and B below. [Show all steps with structure of all intermediates and necessary reagents). A. 3-butyl-2-tetradecanone B. 2-propylpentadecanoic acid
Question 3: The above reaction (using H2SO4/Heat) causes a number of unwanted side products to form...
Question 3: The above reaction (using H2SO4/Heat) causes a
number of unwanted side products to form (a big mess). Propose a
better synthesis for the product using the same starting materials.
Show the reagents and intermediate steps to complete the
synthesis.
The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete...
6.) Synthesis: Show how the following synthetic conversions may be carried out. Include structures of all...
6.) Synthesis: Show how the following synthetic conversions may be carried out. Include structures of all intermediate compounds as well as all reagents used in the conversions. (NO ELECTRON PUSHING MECHANISM SHOULD BE SHOWN HERE!!!) H H a.) H H HzC CH2CH3
Draw the mechanism for the reaction shown below: o This mechanism requires 6 distinct steps This...
Draw the mechanism for the reaction shown below: o This mechanism requires 6 distinct steps This is an acid-catalyzed reaction, use the H30+ in your mechanism o Be sure to include all curved arrows to show the movement of electrons Be sure to include all lone pairs and formal charges on atoms, as necessary For each step in your mechanism, label it based on the type of mechanism step it is H H :N-H
1. Draw the line structures and arrange the following substrates in order of increasing SN2 reactivity...
1. Draw the line structures and arrange the following substrates in order of increasing SN2 reactivity with NaCN: Bromoethane, 1-chloro-3,3-dimethylpentane, 1-chloro-2,2-dimethylpentane, and 2-bromo-2- methylpentane. (1 pt) 2. Design a synthetic route for the following conversion of methylcylohexane into compound A using retrosynthesis analysis. You may use any other reagents that you need. (1 pt) 3. Predict which of the following two compounds will undergo an E2 reaction more rapidly in presence of EtONa/EtOH. Draw the reaction product(s) and the mechanism...
(a) The reaction of esters with Grignard reagents is an excellent technique for the preparation of...
(a) The reaction of esters with Grignard reagents is an excellent technique for the preparation of tertiary alcohols with two identical groups e.g. 2-methyl-2-butanol. Outline all steps in the Grignard synthesis of 2-methyl-2-butanol from methyl propionate. Include all relevant reagents and structures of intermediates. OCH CH3 OH Methylpropionate 2-Methyl-2-butanol (b) Outline all steps in the synthesis of cyclohexanecarboxylic acid from diethyl malonate. Include all relevant reagents and structures of intermediates. соон هلته Eto OEt Diethyl malonate Cyclohexanecarboxylic acid (c) Draw...
Questions 6-8: Phthalic anhydrides are used a lot in synthesis. In 2013 they were used to...
Questions 6-8: Phthalic anhydrides are used a lot in synthesis. In 2013 they were used to create potential anti-inflammatory agents by reacting with glycine to create Phthaloylglycine. The authors then carried out the following steps to create the final product. Fill in the necessary reagents or products needed. (4 pts) Question 6: Question : OH SOCI heat ethanol pyridine Product A Product B Phthaloylglycine NH3NH2, H2O heat NH2 Question 8: TH trace H2SO4 Product C 9. Mechanism: Draw the curved...
6. (4 pts.) Draw the two resonance structures of the enolate formed from the following reaction: 7. (4 pts) Draw th...
6. (4 pts.) Draw the two resonance structures of the enolate formed from the following reaction: 7. (4 pts) Draw the structure of an alkyl bromide (R-Br) and an alkoxide (R-O) that would provide the most efficient synthesis of the following ether by the Williamson ether synthesis. Target ether 8. (5 pts.) Draw a mechanism for the following E2 reaction. Draw the major product. Be sure to include any necessary H's in your structure as you draw the mechanism. OH...
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: OH H3C- ??? + CH3 OH X steps Propose...
^ the top has been answered already
Consider the following reaction: OH Н4С H,SO CH3 + ОН A Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: ОН. HzC...
6. Using either malonic ester synthesis or acetoacetic ester synthesis, outline a reaction scheme in each case to show how you will synthesize compounds A and B below. [Show all steps with structure of all intermediates and necessary reagents). A. 3-butyl-2-tetradecanone B. 2-propylpentadecanoic acid
Question 3: The above reaction (using H2SO4/Heat) causes a
number of unwanted side products to form (a big mess). Propose a
better synthesis for the product using the same starting materials.
Show the reagents and intermediate steps to complete the
synthesis.
The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete...
6.) Synthesis: Show how the following synthetic conversions may be carried out. Include structures of all intermediate compounds as well as all reagents used in the conversions. (NO ELECTRON PUSHING MECHANISM SHOULD BE SHOWN HERE!!!) H H a.) H H HzC CH2CH3
Draw the mechanism for the reaction shown below: o This mechanism requires 6 distinct steps This is an acid-catalyzed reaction, use the H30+ in your mechanism o Be sure to include all curved arrows to show the movement of electrons Be sure to include all lone pairs and formal charges on atoms, as necessary For each step in your mechanism, label it based on the type of mechanism step it is H H :N-H
1. Draw the line structures and arrange the following substrates in order of increasing SN2 reactivity with NaCN: Bromoethane, 1-chloro-3,3-dimethylpentane, 1-chloro-2,2-dimethylpentane, and 2-bromo-2- methylpentane. (1 pt) 2. Design a synthetic route for the following conversion of methylcylohexane into compound A using retrosynthesis analysis. You may use any other reagents that you need. (1 pt) 3. Predict which of the following two compounds will undergo an E2 reaction more rapidly in presence of EtONa/EtOH. Draw the reaction product(s) and the mechanism...
(a) The reaction of esters with Grignard reagents is an excellent technique for the preparation of tertiary alcohols with two identical groups e.g. 2-methyl-2-butanol. Outline all steps in the Grignard synthesis of 2-methyl-2-butanol from methyl propionate. Include all relevant reagents and structures of intermediates. OCH CH3 OH Methylpropionate 2-Methyl-2-butanol (b) Outline all steps in the synthesis of cyclohexanecarboxylic acid from diethyl malonate. Include all relevant reagents and structures of intermediates. соон هلته Eto OEt Diethyl malonate Cyclohexanecarboxylic acid (c) Draw...
Questions 6-8: Phthalic anhydrides are used a lot in synthesis. In 2013 they were used to create potential anti-inflammatory agents by reacting with glycine to create Phthaloylglycine. The authors then carried out the following steps to create the final product. Fill in the necessary reagents or products needed. (4 pts) Question 6: Question : OH SOCI heat ethanol pyridine Product A Product B Phthaloylglycine NH3NH2, H2O heat NH2 Question 8: TH trace H2SO4 Product C 9. Mechanism: Draw the curved...
6. (4 pts.) Draw the two resonance structures of the enolate formed from the following reaction: 7. (4 pts) Draw the structure of an alkyl bromide (R-Br) and an alkoxide (R-O) that would provide the most efficient synthesis of the following ether by the Williamson ether synthesis. Target ether 8. (5 pts.) Draw a mechanism for the following E2 reaction. Draw the major product. Be sure to include any necessary H's in your structure as you draw the mechanism. OH...
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